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    Item type:Publication,
    Preparing transparent cobalt-doped ZnO thin films by DC magnetron sputtering
    (2017-01-01)
    Panyajirawut, Pongladda
    ;
    Pratumsuwan, Nattha
    ;
    Meesombad, Kornkamon
    ;
    Thanawattana, Kridsana
    ;
    Chingsungnoen, Artit
    Thin films of cobalt-doped ZnO were prepared by DC magnetron sputtering on glasses. The cobalt dopant concentration was at 3%wt. The sputtering power was set at 200 watts and sputtered for 20 mins. All films are transparent. The films were then annealed at 100-500 °C under air atmosphere. Crystal structural and optical properties of the films were characterized by XRD and UV-Vis, respectively. The XRD patterns show peaks corresponding to (002) plane indicate thin films obtain hexagonal wurtzite structure. The effects of annealing temperature on crystal structure and optical properties were discussed.
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    Item type:Publication,
    Preparation, characterization and finite element computation of Cu(Al 1/2Fe1/2)O2 Delafossite-oxide themoelectric generator module
    (2014-09-02)
    Ruttanapun, Chesta
    ;
    Jindajitawat, Phumin
    ;
    Buranasiri, Prathan
    ;
    Naenkieng, Daengdesh
    ;
    Boonyopakorn, Narongchai
    The CuAl<inf>1/2</inf>Fe<inf>1/2</inf>O<inf>2</inf> delafossite oxide has been synthesized by solid state reaction method for studying thermoelectric properties and measuring thermoelectric generator output electric power. The Finite Element technique was used to compute the output voltage of thermoelectric generator in applying temperature difference on a single bar and a module model with compared to the measurement results. The measurement results of positive sign Seebeck coefficient confirm the p-type conductor of the sample. The properties of Seebeck coefficient, electrical conductivity, and thermal conductivity are range from 260 to 310V/K, from 7 to16 S/cm and from 2.5 to 3.5 W/cm-K,respectively, in the temperature range of 300 to 960 K. The output voltage of the single bar in dimension 4.2 × 2.5 × 20 mm <sup>3</sup> obtained 0.5 to 3 mV on applying temperature difference from 1 to 10 K closely to the Finite Element result. The computing results of the thermoelectric single bar and module in high temperature reveal the output electric voltage of CuAl<inf>1/2</inf>Fe<inf>1/2</inf>O<inf>2</inf> oxide raises with the temperature and the number of thermoelectric leg increase. In important results, the high value of electric voltage is obtained 0.2 and 0.4 V for the single bar and the module at 950 K. © 2014 Taylor & Francis Group, LLC.
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    Item type:Publication,
    High temperature thermoelectric properties of delafossite CuBO2
    (2014-01-01)
    Ruttanapun, Chesta
    ;
    Jindajitawat, Phumin
    ;
    Buranasiri, Prathan
    ;
    Thowladda, Warawoot
    ;
    Neeyakorn, Worakarn
    CuBO<inf>2</inf> is prepared by a solid-state reaction method to investigate thermoelectric properties in high temperature. The XRD result confirms the CuBO<inf>2</inf> compound existing in this method. The Seebeck reveals the compound displays p-type thermoelectric material. The experimental results of electrical resistivity exhibited results of 0.004 S/cm to 0.038 S/cm with the temperature range of 650 to 830 K. The Seebeck value is in the range of 450 μV/K to 950 μV/K, and the thermal conductivity is in the range of 1.4 × 10<sup>-5</sup> to 5.3 × 10<sup>-5</sup> W/m-K<sup>2</sup> with the same temperature. The maximum PF and ZT is 5.3 × 10<sup>-5</sup> W/m-K<sup>2</sup> and 0.0016, respectively, at 960 K. This work demonstrates that the CuBO<inf>2</inf> delafossite-oxide compound displays the p-type thermoelectric materials. © 2014 IEEE.
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    Item type:Publication,
    Reinvestigation thermoelectric properties of CuAlO2
    (2014-01-01)
    Ruttanapun, Chesta
    ;
    Kosalwat, Wattana
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    Rudradawong, Chalermpol
    ;
    Jindajitawat, Phumin
    ;
    Buranasiri, Prathan
    Bulk CuAlO2 delafossite has been synthesized by solid state reaction to reinvestigate the thermoelectric properties. The electrical conductivity, Seebeck coefficient and thermal conductivity were measured in a high temperature range of 300 to 960 K. The result of positive sign of Seebeck coefficient confirms p-type nature of CuAlO2 compund. The results of bulk sample for Seebeck coefficient, the electrical conductivity and thermal conductivity are range of 900 to 300 μV/K, of 0.01 to 2 S/cm, and of 3.5 W/mK to 1.5 W/mK. The maximum ZT value of bulk sample is 0.017 at a 960 K. These results can be concluded that the bulk CuAlO2 by solid state state displays thermoelelctric material.