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    Rheological Performance of Asphalt Mastics Incorporating Shale and Pumice as Alternative Mineral Fillers
    (2026-05-01)
    Chamwon, Suwaphit
    ;
    Hutabarat, Multazam
    ;
    Chaturabong, Preeda
    This study investigates the hypothesis that mineral fillers with distinct surface characteristics, mineralogical compositions, and morphologies exhibit different reinforcement mechanisms in asphalt mastics. Shale and pumice were evaluated as alternative mineral fillers and compared with conventional granite and limestone at 20% and 30% filler-to-asphalt (F/A) ratios by volume. Filler characterization included X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), specific surface area (SSA), and hydrophilicity coefficient (HC) measurements. Rheological characterization was performed using dynamic shear rheometer, including temperature sweep, frequency sweep master curves, multiple stress creep recovery (MSCR), linear amplitude sweep (LAS), and Glover–Rowe (G–R) analyses. Pumice, dominated by amorphous volcanic glass with the highest SSA (59.18 m²/g), exhibited rutting-dominant modification with the highest complex modulus enhancement (7.3–9.4 times at 30% F/A) and lowest non-recoverable creep compliance. Shale, composed primarily of quartz and kaolinite with layered morphology and moderate SSA (43.00 m²/g), demonstrated balanced rheological response and achieved the longest fatigue life (Nf,5% = 45,200 cycles at 20% F/A). These findings demonstrate that filler-specific reinforcement mechanisms are governed by mineralogical composition and morphology, supporting performance-based filler selection tailored to climatic and loading conditions.
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    EFFECT OF h-BN AS AN ADDITIVE ON PHYSICAL AND MECHANICAL PROPERTIES OF Al2TiO5 COMPOSITE
    (2023-01-01)
    Treetornkeerati, Paramapat
    ;
    Hankoy, Montree
    ;
    Kitiwan, Mettaya
    ;
    Rodchom, Mana
    ;
    Vichaphund, Supawan
    Aluminum titanate (Al<inf>2</inf>TiO<inf>5</inf>) is a promising material for high-temperature applications due to its low thermal expansion, high melting point, and excellent corrosion resistance. In this study, the effect of h-BN addition on the properties of Al<inf>2</inf>TiO<inf>5</inf> composites was investigated. The composites were prepared by sintering a mixture of Al<inf>2</inf>O<inf>3</inf> and TiO<inf>2</inf> at a 1:1 molar ratio, with varying amounts of h-BN (5-20 mol%) added to the mixture. The samples were sintered at 1,500ºC for 4 h in N<inf>2</inf> atmosphere, and the bulk density, porosity, phase transition, microstructure, flexural strength, and hardness of the composites were investigated. XRD analysis confirmed the presence of Al<inf>2</inf>TiO<inf>5</inf>, Al<inf>2</inf>O<inf>3</inf>, and Al<inf>18</inf>B<inf>4</inf>O<inf>33</inf> phases in the composites. The addition of h-BN in increasing amounts from 5 to 20 mol% resulted in a gradual improvement in the bulk density, flexural strength, and hardness of the Al<inf>2</inf>TiO<inf>5</inf> composites. The composite with the highest h-BN content (20 mol%) exhibited a bulk density of 3.12 g/cm<sup>3</sup>, as well as the highest flexural strength and hardness values of 123.6±8.9 MPa and 11.2±4.1 GPa, respectively.
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    Microstructure of ITO for Transparent Electrode on Glass Slide Prepare by RF Sputtering Technique
    (2021-05-29)
    Sangwaranatee, N.
    ;
    Srithanachai, I.
    ;
    Niemcharoen, S.
    Indium tin oxide (ITO) is an absorber photovoltaic material and widely used for semiconductor work for long time. ITO has characteristics by high transparent and low resistivity that can use for electrode of photodetector. Area of photodetector has use for metal contact but if change metal contact to transparent contact will get more photocurrent. However, this paper will investigate microstructure of ITO by analyze physical properties of material by various deposite time. The results show that transparent properties show around 97% at growth 1h and annealing at 500 C. XRD results show ITO peak (222), (400), (622) and (441) at sputtering time 60 mins.
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    Physicochemical characterization of forest and sugarcane leaf combustion's particulate matters using electron microscopy, EDS, XRD and TGA
    (2021-01-01)
    Oo, Hay Mon
    ;
    Karin, Preechar
    ;
    Chollacoop, Nuwong
    ;
    Hanamura, Katsunori
    Physical characteristics and quantitative elemental composition of PM and residual ash produced from sugarcane leaves (SCL) combustion were investigated using TEM-EDS compared with forest leaves (FRL). SEM-EDS was used to analyze the microstructure and chemical composition of biomass raw leaves and PM. XRD analysis was also performed to investigate the characterization of the crystalline nanostructure, structure of PM, and residual ash compared to the TEM image processing method. The oxidation kinetics of biomass raw materials, PM, and residual ash were investigated by TGA. The morphology of fine and ultrafine agglomerate structure of SCL soot and residual ash are not significantly different from the FRL soot and residual ash. The average diameter sizes of single primary nanoparticles of SCL and FRL soot are approximately 37 nm and 35 nm, while the sizes of residual ash are about 18 nm and 22 nm, respectively. The single primary nanoparticles of soot are mainly composed of curve line crystallites of carbon fringes, while residual ash is composed of straight-line lattice fringes. The average fringe lengths of SCL and FRL soot are about 1.25 nm and 1.04 nm from the outer shell and 0.89 nm and 0.74 nm from the inner core. The interlayer spacing of curve line carbon fringes of SCL and FRL soot is approximately 0.359 nm and 0.362 nm by the TEM image analysis and it was matched with XRD analysis. The biomass PMs are mainly composed of soot, Si, Ca, and K compounds: SiO<inf>2</inf>, CaCO<inf>3</inf>, and KCl.