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    High-performance triboelectric and piezoelectric nanogenerator enabled by BF-BT-NZN multifunctional ceramic filler
    (2025-10-01)
    Sumang, Rattiphorn
    ;
    Jantaratana, Pongsakorn
    ;
    Charoonsuk, Thitirat
    ;
    Vittayakorn, Naratip
    ;
    Bongkarn, Theerachai
    The development of efficient and flexible energy-harvesting materials is essential for advancing self-powered electronic devices. In this study, we report the fabrication of flexible composite films by incorporating (1-x)(0.75BiFeO<inf>3</inf>-0.25BaTiO<inf>3</inf>)-xNd(Zn<inf>0.67</inf>Nb<inf>0.33</inf>)O<inf>3</inf>,abbreviated as (BF-BT-NZN), ceramic powder into a PDMS matrix, with filler contents ranging from 5 to 25 wt%. The optimized 10 wt% composite film demonstrated a maximum output voltage of 112.24 V and a current of 5.69 µA approximately 11 and 18 times higher than pure PDMS, respectively. Following a poling treatment, the output further increased to 149.54 V and 10.71 µA. The film exhibited excellent flexibility and durability, enabling practical applications such as powering LEDs, a digital watch, and charging capacitors. These results highlight the potential of BF-BT-NZN/PDMS composites as high-performance materials for wearable energy-harvesting applications.
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    High-performance flexible lead-free piezo-antiferroelectric based on NaNbO3/PDMS composites for energy harvesting application
    (2024-12-01)
    Sumang, Rattiphorn
    ;
    Charoonsuk, Thitirat
    ;
    Vittayakorn, Naratip
    ;
    Panpho, Phakakorn
    To bring the rapidly advancing technology of energy harvesters into commercial use, further development is required for devices that can enhance output performance, flexibility, ease of fabrication, and low cost. A hybrid concept is a promising method. It combines between the piezoelectric nanogenerator (PENG) and the triboelectric nanogenerator (TENG) to provide a high-performance nanogenerator. This study introduced a high-performance hybrid PENG and TENG device that operates using a NN-BNT/PDMS composite film. The NN-BNT/PDMS composite based nanogenerators were fabricated with varying NN-BNT content. Then, dielectric test and electrical properties were investigated. Adding NN-BNT into the PDMS composite film resulted in a higher dielectric constant compared to pure PDMS, leading to increase of electrical output. Under the optimal condition of a 3 wt%. NN-BNT composite based hybrid nanogenerator, the electrical output was significantly enhanced, reaching 40 V, 0.95 μA/cm<sup>2</sup>, and 200 μW/cm<sup>2</sup> compared to pure PDMS. This nanogenerator further used to the charging of a capacitor to a voltage of around 1 V within 5 s and also powered multiple LEDs. The successful development of this highly efficient NN-BNT/PDMS composite film-based hybrid concept sheds light on energy harvesting devices.