Limmun, Warunee
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Preferred name
Limmun, Warunee
Alternative Name
Limmun, W.
Main Affiliation
Email
warunee.li@kmitl.ac.th
14 results
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Item type:Publication, Sustainable Valorization of Salak Peel Waste: Regeneration of Biochar for Lead Removal from Wastewater(2026-01-01) ;Buakhiao, Phruektinai; ;Jamkamon, Aud; This study evaluates the effects of pyrolysis temperature (600°C and 800°C, denoted as SP600 and SP800) and regeneration reagents on lead (Pb²⁺) adsorption performance of biochar derived from salak peels. Moreover, the lead removal efficiency and adsorption efficiency after several regeneration cycles under appropriate conditions were also investigated. The results indicate that increasing the pyrolysis temperature significantly enhances lead removal efficiency and adsorption capacity, with biochar pyrolyzed at 800°C and loaded with lead (SP800Pb) exhibiting the highest initial lead adsorption performance. However, upon regeneration using hydrochloric acid (HCl) and sodium nitrate (NaNO₃) at various concentrations, SP600Pb demonstrated higher lead removal performance than SP800Pb across all conditions. Specifically, SP600Pb regenerated by 0.1M HCl exhibited the highest lead desorption efficiency and removal efficiency. Furthermore, after five consecutive adsorption-regeneration cycles, the biochar regenerated by 0.1M HCl (SP600RPb) exhibited a suitable removal efficiency of 83.91 ± 0.10 and a desorption efficiency of 148.73 ± 0.13. The observed desorption efficiency exceeding 100 was attributed to the accumulated release of Pb²⁺ ions during successive regeneration cycles, which indicates enhanced ion-exchange dynamics over time. Therefore, biochar pyrolyzed at 600°C and regenerated using 0.1M HCl is appropriate for the reuse of biochar in lead adsorption, promoting sustainable resource application, cost reduction, and waste minimization in production processes. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Degradation of the endocrine-disrupting 4-nonylphenol by ferrate(VI): biodegradability and toxicity evaluation(2022-03-01); ;Ishikawa, Nao ;Momotori, Jin ;Terasaki, MasanoriSato, Takumu4-Nonylphenol (4-NP) is an endocrine-disrupting and persistent chemical and is partially degraded in conventional wastewater treatment processes. Ferrate(VI) can be used as an environment-friendly oxidizing agent to mediate 4-NP degradation. Thus, this paper evaluates the biodegradability of 4-NP and its degradation products after the addition of ferrate(VI). The biodegradability was examined using NP labeled with <sup>14</sup>C as a tracer and activated sludge microorganisms as an inoculum. The addition of ferrate(VI) to the 4-NP solution spiked with the tracer resulted in no remarkable decrease in the concentration of <sup>14</sup>C, indicating incomplete mineralization of 4-NP and formation of degradation products. The degradation products from 4-NP with Fe(VI) were estimated based on mass spectra, which detected a unique peak at m/z 223 at low intensity. Four hydrogen atoms might have been added to 4-NP by degradation with Fe(VI). In addition, the effect of ferrate(VI) concentration on the estrogenic activity of 4-NP in an aqueous solution was investigated using a yeast bioassay. The results show that estrogenic activity was significantly decreased at a mass ratio of Fe(VI) to 4-NP greater than or equal to 2.5. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Enhanced biodiesel purification using coffee husk bioadsorbents: The role of pyrolysis temperature, KOH activation, and adsorption efficiency(2025-05-01); ; ; ; Ruttanadech, NuttapongThis study evaluates the performance of bioadsorbents derived from coffee husk pyrolyzed at temperatures of 600, 700, and 800 °C (CH600, CH700, and CH800), along with activated CH700 (ACH700), in biodiesel purification. The results indicate that CH700 significantly enhances biodiesel purity, with optimal purification conditions achieved at a dosage of 2 wt% CH700, a stirring rate of 400 rpm, and a contact time of 45 min. CH700 demonstrated modest performance, achieving approximately 20 % removal of methanol and water. However, after activation with potassium hydroxide (KOH), ACH700 demonstrated improved efficiency, achieving 96.92 % methanol removal and 39.46 % water removal. ACH700 also refined biodiesel quality to meet EN14214 standards and maintained a higher biodiesel yield compared to other adsorbents. The bioadsorption process is influenced by the chemical interactions between the surface functional groups of the bioadsorbent and the contaminants, which is further enhanced by the optimized pore structure of ACH700. The use of ACH700 represents a novel and highly effective approach to biodiesel purification, combining both technical efficiency and economic feasibility. Furthermore, the valorization of agricultural waste adds significant environmental benefits, reinforcing the potential of ACH700 for large-scale biodiesel production. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Eco-friendly magnetic biochar from Leb Mu Nang banana peel: Response surface methodology optimization for Cd(II) adsorption from synthetic wastewater(2024-02-01) ;Limmun, Wanida; ;Borkowski, John J. ;Ishikawa, NaoPairintra, RattanachaiMagnetic biochar derived from Leb Mu Nang banana peel waste is introduced as a novel precursor for Cd(II) removal from synthetic wastewater. This study comprehensively evaluates and optimizes variable factors, including initial Cd(II) concentration, magnetic biochar (MLP) dosage, adsorption time, and initial pH level, using the Response Surface Methodology (RSM). A Cd(II) removal efficiency of up to 93.4 % is reached under the conditions of a 50 mg/L initial concentration, 5 g/L MLP dosage, 24 h of adsorption time, and a solution pH of 8. The pseudo-second-order and Langmuir models accurately represent the kinetics and isotherm adsorptions, highlighting ion exchange, surface complexation, and precipitation as primary adsorption mechanisms. The magnetic biochar derived from Leb Mu Nang banana peels shows promise for efficient Cd(II) removal with easy post-adsorption separation. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effects of Coffee Form and Distributor Hole Angle on The Fluidization Behavior and Specific Energy Consumption in The Fluidized Bed Machine(2021-08-01); ; Sansiribhan, SansaneeThe fluidized bed technique was applied to use with the Robusta coffee in this research. fluidization behavior and specific energy consumption were investigated under various coffee forms and distributor hole angles. Moreover, the minimum fluidization velocity (Vmf) was also determined. Experiments are carried out in a sample bed height of 5 cm with ambience air. In this study, two coffee forms (Ripe coffee cherries; RCC and parchment coffee; PC) and three distributor hole angles (45°, 60° and 90°) are examined. The experimental result shown that the fluidization behavior is influenced by coffee form and distributor hole angle. The RCC and distributor hole angle of 60° provided the low pressure drop throughout the superficial air velocity. The low values of Vmf and SEC were also achieved in the RCC and distributor hole angle of 60°. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Low-Cost Near-Infrared Spectroscopy for Rapid Prediction of Biodiesel Properties: Acid Value, Density, Viscosity, and Water Content(2026-03-31); ;Thongphut, Chitwadee; Partial least squares (PLS) regression, combined with various spectral pre-processing techniques, was employed to compare the performance of two diode array near-infrared (NIR) spectrometers in predicting key biodiesel quality parameters, including acidity, viscosity, density, and water content. An AvaSpec-Mini4096CL NIR spectrometer, operating within the 350–1100 nm wavelength range, was used as the representative shortwave near-infrared (SW-NIR) spectrometer, while a NIRQuest512 spectrometer, covering the 900–1700 nm range, was employed as the longwave near-infrared (LW-NIR) spectrometer. Both spectrometers were equipped with a transflection probe for spectral collection from oil palm-based biodiesel samples. The SW-NIR spectrometer outperformed the LW-NIR spectrometer. The optimal PLS models achieved root mean square errors of prediction (RMSEP) of 0.0037 mg KOH/g for acidity, 0.062 cSt (mm<sup>2</sup>/s) for viscosity, 2.67 kg/m<sup>3</sup> for density, and 59.14 mg/kg for water content, highlighting the potential of compact SW-NIR spectrometers as effective, low-cost tools for rapid biodiesel quality monitoring. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Preparation and evaluation of blend polymer films for wound dressing using vancomycin-loaded polycaprolactone and carboxymethyl cellulose via crosslinking methods: Effect of mechanical strength, antibacterial activity, and cytotoxicity(2024-03-01) ;Meedecha, Paweena; ;Eawsakul, Komgrit ;Ongtanasup, TassaneeTambunlertchai, SupreedaPolycaprolactone (PCL) and carboxymethyl cellulose (CMC) are two materials with beneficial properties for wound healing applications. Here, the simple preparation of PCL/CMC polymer films via the crosslinking method was demonstrated for the first time. The polymer films represented the suitable properties of liquid absorption and tensile strength to be used as a wound dressing. The blend polymer films can also load the vancomycin, which prolongs the drug release for effectiveness against S. aureus. The trifluoroethanol showed less toxicity in comparison with other crosslinking agents. This process can also be applied further in other medical devices and wound healing applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Sustainable tropical fruit peel waste biochars for enhanced cadmium and lead adsorption: mechanistic insights and optimization using response surface methodology and backpropagation neural networks(2025-08-01) ;Limmun, Wanida; ;Maneesri, Wisit ;Pewpa, OrrawanHeavy metal contamination, particularly from cadmium (Cd(II)) and lead (Pb(II)), presents a severe environmental challenge due to its toxicity and persistence. This study explores an innovative approach by utilizing abundant yet underutilized tropical fruit peel waste to produce biochars that serve as effective, sustainable adsorbents for heavy metal remediation. Biochars derived from banana peels (BP) and Monthong durian shells (DS) were synthesized via pyrolysis at 400–800 °C and evaluated for their physicochemical properties and adsorption efficiency. The DS600 biochar exhibited the highest adsorption capacity, removing Cd(II) (40.37 mg/g) and Pb(II) (51.74 mg/g), surpassing BP600 (40.22 mg/g and 47.23 mg/g, respectively). This study introduces a dual-modeling framework by integrating response surface methodology (RSM) with backpropagation neural network (BPNN) to optimize adsorption conditions and enhance predictive accuracy. The optimized conditions achieved over 99% removal efficiency, with R<sup>2</sup> > 0.98 and MSE < 0.05, confirming the robustness of the model-based predictions. The study highlights the superior adsorption performance of DS600 biochar, with adsorption mechanisms influenced by pH, dosage, and biochar properties. In contrast to conventional studies that focus solely on equilibrium adsorption or rely on statistical models, this work pioneers the use of tropical fruit peel biochar in heavy metal remediation, providing quantitative insights into process optimization and practical scalability. The findings demonstrate the potential for valorizing agricultural waste into high-performance adsorbents, advancing cost-effective and sustainable water treatment technologies. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Charcoal briquette production from waste in the coffee production process using hydrothermal and torrefaction techniques: A comparative study with carbonization technique(2022-10-20); ; ;Ruttanadech, Nuttapong; This research aimed to study charcoal briquette production from coffee production waste, i.e., coffee parchment (CP) and coffee cherry pulp (CCP). The carbonization technique (CT) was studied in five mixtures (CP and CCP ≈ 0–90%) and three pressures (1000–1600 psi) to determine the appropriate conditions. The torrefaction technique (TT) and hydrothermal technique (HT) were subsequently performed under proper conditions from the CT to investigate further the fit temperatures (200–260 °C) and reaction times (40–120 min). The fuel characteristics were examined regarding the calorific value (CV), proximate and ultimate analyses, mechanical properties, and utilization properties. The results demonstrated the notable influence of interaction between the mixture and pressure factors and individual mixture on the fuel properties, whereas personal pressure have an insignificant effect. The ratio of CP ≈ 90% and binder ≈10% at a pressure of 1600 psi in the CT prepared appropriate fuel properties (calorific value ≈ 27 MJ/kg, fixed carbon content ≈ 65%). Interestingly, almost all conditions of the TT and HT provided greenhouse gas emissions lower than the CT. The TT and HT at 260 °C for 120 min provided high calorific values (25–26 MJ/kg) with other fuel characteristics in the acceptable standard, except for the fixed carbon content. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Biodiesel Washing by the Prototype of a Biodiesel Washing Machine with Biochar(2025-11-01) ;Fonghiransiri, Surasak; ;Choola-Aied, Orasa; Currently, the prevalent technique for biodiesel washing entails the utilization of water in the purification process. Nevertheless, this method incurs substantial biodiesel loss and gives rise to wastewater, posing potential environmental consequences. Hence, this study aimed to utilize biochar for removing impurities from biodiesel by using a prototype of a biodiesel washing machine with biochar. The effects of the propeller blade number, propeller blade angle, and mixing time on the capability to eliminate impurities in biodiesel were elucidated. The results indicated that the biodiesel washing machine can increase biodiesel yield by up to 2.49% (91.54%) compared to the water washing process (89.05%). The increased propeller blade number, angle, and mixing time can improve the acidity (24.50-64.04%) and water content removal (42.61-79.56%). Consequently, this led to a decrease in density (865.85-886.83 kg/m<sup>3</sup>) and viscosity (3.997-4.321 cSt). The conditions with the best biodiesel properties were five propeller blades, a propeller blade angle of 60 degrees, and a mixing time of 30 minutes. These conditions provided the 63.88% acid removal, 79.49% water content removal, viscosity of 878.92 kg/m<sup>3</sup> and density of 4.208 cSt. Moreover, the methanol and glycerol contents were 0.02% wt. and 0.04% wt., respectively. These properties meet the ASTM 6751 and EN 14214 biodiesel standards.
