Seeharaj, Panpailin

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Seeharaj, Panpailin
Alternative Name
Seeharaj, P.
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panpailin.se@kmitl.ac.th

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    Item type:Publication,
    Effect of sintering additives on barium cerate based solid oxide electrolysis cell for syngas production from carbon dioxide and steam
    (2018-05-01)
    Likhittaphon, S.
    ;
    Pukkrueapun, T.
    ;
    Seeharaj, P.
    ;
    Wetwathana Hartley, U.
    ;
    Laosiripojana, N.
    The effect of sintering additives (NiO, Co<inf>2</inf>O<inf>3</inf>, and ZnO) on the performance of barium-cerate-based solid oxide electrolysis cell (SOEC) is investigated. The performance of the SOEC with different sintering additives is determined in terms of relative density, electrochemical performance, and catalytic activity toward reverse water gas shift reaction. BaCeO<inf>3</inf> (BC) and BaCe<inf>0.9</inf>Gd<inf>0.1</inf>O<inf>3−δ</inf> (BCG) are synthesized using conventional precipitation method, comparing to ultrasonic-assisted precipitation. The sintering additives promote both densification and grain growth. The relative density of the BCG without sintering additive is 69% while that of the BCG with 1 wt% of Co<inf>2</inf>O<inf>3</inf>, NiO and ZnO is 95%, 95% and 88%, respectively. The SEM images indicate that the BCG with sintering additives exhibits dense grains with relatively large grain size. Although the BGC with NiO and Co<inf>2</inf>O<inf>3</inf> exhibit maximum relative density, the sample with ZnO shows relatively highest conductivity with the lowest activation energy of conduction and the sample with NiO provides the largest CO yield and CO<inf>2</inf> conversion. The activation energy of conduction is found to be 375.41, 70.06, 66.86 and 61.80 kJ mol<sup>−1</sup> for BCG, BCG with 1 wt% Co<inf>2</inf>O<inf>3</inf>, NiO and ZnO, respectively. The BCG with 1 wt% NiO provides the highest CO<inf>2</inf> conversion and CO yield at temperature below 700 °C (62% CO<inf>2</inf> conversion and 32% CO yield at 700 °C). Temperature program of oxidation (TPO) reveals that carbon deposition can cause the low CO yield at the operating temperature above 700 °C.
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    Low-temperature preparation of BaCeO3 through ultrasonic-assisted precipitation for application in solid oxide electrolysis cell
    (2015-06-20)
    Kim-Lohsoontorn, P.
    ;
    Paichitra, C.
    ;
    Vorathamthongdee, S.
    ;
    Seeharaj, P.
    Barium cerate (BaCeO<inf>3</inf>) was synthesized using conventional precipitation and ultrasonic-assisted precipitation. The effect of precipitation parameters (precipitation precursor, precipitation agent, agent concentration and temperature) significantly affected %perovskite formation and crystallite size of the product. Precipitation with 1 M (NH<inf>4</inf>)<inf>2</inf>C<inf>2</inf>O<inf>4</inf> induced the formation of a single-phase BaCeO<inf>3</inf> while precipitation with 5-20 M NaOH provided a mixed phase of BaCeO<inf>3</inf> and CeO<inf>2</inf>. The %perovskite increased as increasing precipitation temperature; however, the crystallite size of the product also increased. Increasing ultrasonic intensity (30 and 150 W cm<sup>-2</sup>) during precipitation was found to increase the %perovskite and to reduce crystallite size. The precipitation with 1 M (NH<inf>4</inf>)<inf>2</inf>C<inf>2</inf>O<inf>4</inf> agent, using ultrasonic intensity at 150 W cm<sup>-2</sup>, provided single phase BaCeO<inf>3</inf> with crystallite size of 18.4 nm after calcination at 900 °C for 4 h. The electrochemical performance of the BaCeO<inf>3</inf> cell under steam electrolysis condition (controlled voltage from OCV to 1.5 V; 20% H<inf>2</inf>O, 40% H<inf>2</inf>, and 40% N<inf>2</inf>) was measured (600-800 °C) and the activation energy of conduction was calculated to be 0.78 eV.