Vittayakorn, Naratip

Preferred name

Alternative Name

Vittayakorn, N.

Vittayakorn, Narathip

Main Affiliation

School of Science

naratip.vi@kmitl.ac.th

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Phase structure, microstructure, electrical and energy storage properties of SBNLT lead free ceramics with Zr4+ substituted into B-sites
(2024-09-01)
Sinkruason, Thanapon
;
Luangpangai, Anupong
;
Julphunthong, Phongthorn
;
Rittidech, Aurawan
;
Pulphol, Phieraya
Lead-free (Sr<inf>0.3</inf>Bi<inf>0.35</inf>Na<inf>0.335</inf>Li<inf>0.015</inf>) (Ti<inf>1−x</inf>Zr<inf>x</inf>) O<inf>3</inf> ceramics (SBNLT<inf>1−x</inf>Zr<inf>x</inf>) with x = 0–0.04 were prepared via the solid-state combustion technique using glycine as the fuel. The influence of Zr content on the phase structure, microstructure, electrical properties, and energy storage properties of the SBNLT<inf>1−x</inf>Zr<inf>x</inf> ceramics was examined. The presence of a pure perovskite phase was shown by X-ray diffraction (XRD) patterns, with the coexistence of rhombohedral and tetragonal phases in all samples, as certified by the Rietveld refinement method. Scanning electron microscopy (SEM) was utilized to observe the morphology of the SBNLT<inf>1−x</inf>Zr<inf>x</inf> ceramics, which revealed cube shaped grains with anisotropic growth. Average grain size increased from 2.01 to 2.49 µm when x increased from 0 to 0.01 and then reduced with further increases in Zr content. The maximum dielectric constant dropped from 4667 to 2990 when x increased from 0 to 0.04, caused by a shift from the morphotropic phase boundary (MPB). The maximum polarization (P<inf>max</inf>) of 29.18 µC/cm2, energy storage density (W<inf>total</inf>) of 0.851 J/cm3 and recoverable energy storage (W<inf>rec</inf>) of 0.609 J/cm3 were achieved when x = 0.02.
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Enhanced electrical and energy storage performances of Fe, Sb co-doped BNBCTS ceramics synthesized via the solid-state combustion technique
(2024-12-01)
Kornphom, C.
;
Saenkam, K.
;
Yotthuan, S.
;
Vittayakorn, N.
;
Bongkarn, T.
In this study BNBCTS ceramics were co-doped with Fe and Sb to form (Bi<inf>0.5</inf>Na<inf>0.5</inf>)<inf>0.93</inf>(Ba<inf>0.945</inf>Ca<inf>0.055</inf>)<inf>0.07</inf>(Ti<inf>(0.9946-x)</inf>Sn<inf>0.0054</inf>)(Fe<inf>0.5</inf>Sb<inf>0.5</inf>)<inf>x</inf>O<inf>3</inf> ceramics (denoted as BNBCTS-xFS) with various x content and were prepared via the solid-state combustion technique to enhance the electrical and energy storage performance. The effect of co-doping Fe and Sb on the phase formation, defect dipole, microstructure, electrical and energy storage properties of BNBCTS-xFS ceramics was studied. When x content increased from 0.0 to 0.030, the amount of the rhombohedral (R) phase decreased from 51 to 24 % while the tetragonal (T) phase increased from 49 to 76 %. The increased Fe and Sb content increased the defect dipole of singly/doubly charged oxygen-vacancies (V<inf>O</inf>∙/ V<inf>O</inf>∙∙) and caused more Ti4+ to transition to Ti3+, which caused the transition temperature of the ferroelectric phase to relaxor state (T<inf>F-R</inf>) in the ceramics to drop to below room temperature and it exhibited relaxor characteristics at room temperature. The ceramic with an x content of 0.010 had the largest grain size (3.06 μm), excellence ferroelectric properties (P<inf>r</inf> ∼31.04 μC/cm2, P<inf>m</inf> ∼38.98 μC/cm2 and E<inf>c</inf> ∼18.28 kV/cm), the largest electro strain (∼0.175 %) and a large d<inf>33</inf>* of 350 pm/V. Moreover, when x = 0.020, the ergodic relaxor ceramic showed the smallest grain size (1.03 μm), the lowest remanant polarization (P<inf>r</inf>) of 4.52 μC/cm2 and the lowest coercive field (E<inf>c</inf>) of 8.37 kV/cm, at an electric field of 60 kV/cm. More importantly, energy storage properties at the electric breakdown strength (E<inf>b</inf> = 120 kV/cm) of the ceramics with an x content of 0.020 exhibited a recoverable energy storage density (W<inf>rec</inf>) of 1.81 J/cm3, a total energy storage density (W<inf>total</inf>) of 2.95 J/cm3 and an efficiency (η) of 61.30%, with excellent thermal (∼25–150 °C) and frequency stability (∼1–100 Hz). This study provides new insights into the modulation of BNBCTS ceramics with Fe and Sb co-doping, which could effectively improve the electrical properties and energy storage properties of BNBCTS-xFS ceramics.
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Modified energy storage properties of lead-free Sr0.3Bi0.35Na0.335Li0.015TiO3 ceramics with La3+ substitution via the solid-state combustion technique
(2024-12-01)
Sinkruason, Thanapon
;
Luangpangai, Anupong
;
Julphunthong, Phongthorn
;
Rittidech, Aurawan
;
Suthapintu, Aekasit
In this study, the influence of La3+ substitution on the phase structure, microstructure, electrical and energy storage properties of (Sr<inf>0.3</inf>Bi<inf>0.35</inf>Na<inf>0.335</inf>Li<inf>0.015</inf>)<inf>1-x</inf>La<inf>x</inf>TiO<inf>3</inf> (SBNLT-xLa) ceramics with x = 0–0.05, using the solid-state combustion technique, was investigated. X-ray diffraction (XRD) patterns indicated a pure perovskite structure formed, along with coexisting rhombohedral and tetragonal phases in all ceramics. The Rietveld refinement analysis showed the tetragonal phase increased while the rhombohedral phase decreased with increased La3+ content. The morphology of the SBNLT-xLa ceramics displayed polygonal grain shapes and anisotropic grain growth. Average grain sizes increased from 2.01 to 2.43 μm as x increased from 0 to 0.01 and afterwards decreased as x increased further. Both the measured density and maximum dielectric constant (ɛ<inf>m</inf>) decreased from 5.48 to 5.29 g/cm3 and from 4667 to 2313, respectively, when x increased from 0 to 0.05. A decrease in the dielectric properties caused by the phase ratio shifting away from a morphotropic phase boundary (MPB) condition, poor microstructure and low density was produced with La3+ replacement. The maximum polarization (P<inf>max</inf>), remnant polarization (P<inf>r</inf>) and coercive field (E<inf>c</inf>) decreased with increased La3+ content. A decline in P<inf>r</inf> and E<inf>c</inf> improved the energy storage efficiency (ƞ) and energy storage loss (W<inf>loss</inf>), resulting in enhanced energy storage properties. At x = 0.02, the ceramic showed good energy storage properties (W<inf>total</inf> of 0.781 J/cm3, W<inf>rec</inf> of 0.624 J/cm3, W<inf>loss</inf> of 0.157 J/cm3 and ƞ of 79.8%), measured at 60 kV/cm.
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Synthesis of vanadium oxide/titanium dioxide nanocomposites via sonochemical and hydrothermal process and their utilisation for energy storage application
(2014-01-01)
Kahattha, C.
;
Techitdheera, W.
;
Vittayakorn, N.
;
Pecharapa, W.
This work focuses on the synthesis of V<inf>2</inf>O<inf>5</inf>/TiO <inf>2</inf> nanocomposites by sonochemical and hydrothermal process. First, titanium dioxide (TiO<inf>2</inf>) nanopowders were synthesised by sonochemical process using titanium isopropoxide as a titanium source. Meanwhile, hydrothermal process was employed to modify the structure of commercial V <inf>2</inf>O<inf>5</inf> powder to be nanorod-like structure V <inf>2</inf>O<inf>5</inf> to increase its specific surface area. Structural and morphological properties of the composites were characterised by X-ray diffraction, scanning electron microscope and transmission electron microscope. The XRD results indicate that the crystallisation of the composite corresponds to anatase and orthorhombic structures of TiO<inf>2</inf> and V <inf>2</inf>O<inf>5</inf>, respectively. The significant variation of charge storage properties of the composites under ultraviolet irradiation was obtained by varying V<inf>2</inf>O<inf>5</inf> content in the composite. Results suggest that V<inf>2</inf>O<inf>5</inf> loaded into the nanocomposite plays a key role as a storage material of photoelectrons generated by TiO<inf>2</inf> illuminated by ultraviolet irradiation. Copyright © 2014 Inderscience Enterprises Ltd.

Vittayakorn, Naratip

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