Imorb, Karittha

Preferred name

Imorb, Karittha

Alternative Name

Im-orb, Karittha

Im-Orb, Karittha

Im-orb, K.

Main Affiliation

School of Food Industry

karittha.im@kmitl.ac.th

Now showing 1 - 10 of 23

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Process Improvement and Economic and Environmental Evaluation of Bio-Hydrogenated Diesel Production from Refined Bleached Deodorized Palm Oil
(2025-01-01)
Anantpinijwatna, Amata
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Simasatitkul, Lida
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Yooyen, Kanokporn
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Amornraksa, Suksun
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Assabumrungrat, Suttichai
The co-production of BHD with other renewable fuels (i.e., using a novel process involving carbon dioxide utilization to achieve the global sustainability goal) is presented. The three configurations of BHD production from refined bleached deodorized palm oil (RBDPO), including (1) the conventional BHD process with hydrogen recovery (BHD process), (2) the BHD process coupled with the Fischer–Tropsch process (BHD-FT process), and (3) the BHD process coupled with the bio-jet fuel and methanol processes (BHD-BIOJET-MEOH process) are investigated using the process model developed in Aspen Plus. The effect of the operating parameters is studied, and the condition of each process offering the highest BHD yield is proposed. Then, the pinch analysis and heat exchanger network (HEN) design of each proposed process are performed to find the highest energy-efficient configuration. The economic and environmental analysis is later performed to investigate the sustainability performance of each configuration. The conventional BHD process requires less hydrogen and consumes less energy than the others. The BHD-BIOJET-MEOH process is the most economically feasible, offering the highest net present value (NPV) of USD 7.93 million and the shortest payback period of 3 years and 1 month. However, it offers the highest carbon footprint of 0.820 kgCO<inf>2</inf> eq./kg of BHD, and it presented the highest potential environmental impact (PEI) in all categories.
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Design and evaluation of the sorption enhanced steam reforming and solid oxide fuel cell integrated system with anode exhaust gas recirculation for combined heat and power generation
(2017-01-01)
Wiranarongkorn, Kunlanan
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Im-Orb, Karittha
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Ponpesh, Pimporn
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Patcharavorachot, Yaneeporn
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Arpornwichanop, Amornchai
Solid oxide fuel cell (SOFC) is an electrochemical device for power generation with high efficiency and low environmental impact. Due to a high-temperature operation of SOFC, useful heat can be recovered to enhance its system efficiency. Regarding the environmental concern, bio-oil, the renewable liquid fuel, can be applied to SOFC system. In this study, the SOFC integrated with a steam reforming of bio-oil is considered. A sorption enhanced reforming process is studied for the production of high purity hydrogen for SOFC, and the anode gas recirculation in the SOFC system is proposed for the system improvement. Modeling of such an integrated process is performed using Aspen Plus simulator. As heat and power are generated from the SOFC system, the effect of key design parameters; fuel utilization and recirculation ratio of the anode gas, on a heatto-power ratio is analyzed. The system performance regarding to the electrical and thermal efficiencies is also evaluated. The results show that increasing the anode recirculation ratio increases the combined heat and power (CHP) performance, but increasing the fuel utilization decreases the thermal efficiency. It is also found that the appropriate range of heat-to-power ratio of the system varies from 0.24 to 0.89.
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Performance Assessment of Co-Gasification Process for Syngas Production Using Multi-Biomass Feedstocks
(2026-06-15)
Wiranarongkorn, Kunlanan
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Detchusananard, Thanaphorn
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Piroonlerkgul, Pakorn
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Im-orb, Karittha
The investigation focused on alternative energy production from biomass residuals, predominantly located in Northern Thailand, for year-round utilization. The biomass gasification model was created in Aspen Plus. The cassava stalk served as a foundational biomass for blending with additional materials. Increased equivalent ratio (ER) increased syngas yield, while higher gasifying temperatures decreased it. The total energy demand rose with increasing ER, whereas it decreased with higher gasifying temperatures. The gasification process may transition from exothermic to endothermic when the ER exceeds 0.25. The effect of mixing ratio of 1) cassava stalk and 2) rice straw, or 3) cane stalks, or 4) corn stalk at 1:0, 4:1, 3:2, and 2:3 on the gasification performance was investigated. The maximum syngas yield of all mixture cases at each gasifying temperature was achieved at mixing ratio of 2:3 and ER of 0.3. This study discovered blending cassava stalk with seasonal leftovers like rice straw, cane stalks, and corn stalks in a 2:3 ratio generated outstanding syngas year-round in Thailand. For the blended biomass feed rate of 10 kg/h, the maximum syngas yield of 0.356 kmol/h was achieved for the mixture of cassava stalk and rice straw at a gasifying temperature of 900°C.
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Assessment of bio-methanol and electricity co-production via the integration of biomass-to-methanol process, solid oxide electrolyzer, and power generator
(2025-11-01)
Detchusananard, Thanaphorn
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Wiranarongkorn, Kunlanan
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Im-orb, Karittha
The performance assessment of an integrated biomass to methanol and solid oxide electrolyzer with and without a power generation unit (BtM-SOEC-PG and BtM-SOEC), utilizing purge gas from BtM for production of bio-methanol and electricity, is performed. For BtM-SOEC-PG, two utilization routes of low pressure (LP) steam leaving the power generation system (case 1: LP steam is exported to external users (BtM-SOEC-PG-LPEX) and case 2: LP steam is utilized in the process (BtM-SOEC-PG-LPUT)) are examined to determine the impact on process performance of recycling purge gas from BtM to either the methanol reactor or the power generation unit. In all cases, the bio-methanol production increases with increased purge gas recycling, whereas the power generation decreases. The direct CO<inf>2</inf> emissions are also improved with increased recycling. Two BtM-SOEC-PG cases are an exothermic process, and the degree of exothermicity increased with purge gas recycling. However, the BtM-SOEC-PG-LPUT with 90 % purge gas recycling offers a maximum methanol production rate of 15.99 kg/h, and under these conditions, 3.17 kW of electricity is generated and 56.18 % energy efficiency is obtained. The energy efficiency of the BtM-SOEC-PG-LPUT, with 90 % purge gas recycling, could potentially be enhanced by 10.42 % due to pinch analysis and heat exchanger network (HEN) design. Exergy analysis indicates that the gasifier is the primary unit of exergy destruction, followed by the combustion unit and the autothermal reformer (ATR) in the second and third positions, respectively. Furthermore, the BtM-SOEC-PG-LPUT with 90 % purge gas recycling offers a competitive cost of bio-methanol (824.37 USD/ton) compared to BtM-SOEC.
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Exergy and exergoeconomic analyses of sustainable furfural production via reactive distillation
(2021-07-01)
Wiranarongkorn, Kunlanan
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Im-orb, Karittha
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Panpranot, Joongjai
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Maréchal, François
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Arpornwichanop, Amornchai
Lignocellulosic biomass is a potential renewable resource for production of high-value, sustainable products. Furfural is among the important bio-based chemicals in biorefineries. However, the conventional process of furfural production using a reaction-separation network entails low product yield but high fixed and operating costs owing to the complex process of separation. In this study, a process of furfural production via reactive distillation (RD) was investigated and designed based on the concept of process intensification. Exergy and exergoeconomic analyses were applied to evaluate the process performance. When the RD column was operated at its optimal configuration, furfural production of 81.78 kg h−1 was achieved with xylose conversion and furfural yield of 97.9% and 97.4%, respectively. The exergy efficiency of furfural production was 56.41%, while the RD column exhibited the maximum exergy destruction rate among all components with an exergy efficiency of 69.82%. The exergy destruction rate declined with decrease in the reboiler duty of the RD column and increase in xylose concentration. The exergoeconomic analysis revealed that decreasing the reboiler duty had the highest impact on the total cost of furfural production. Decreases in feedstock and catalyst costs as well as interest rate additionally lowered the total cost rate of the system.
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A Review on the Technical and Economic Prospects of Biofuel Production from Integrated Biomass Gasification and Fischer-Tropsch Processes
(2020-01-01)
Im-orb, Karittha
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Arpornwichanop, Amornchai
Concerns in energy shortage and the impact of greenhouse gas emissions motivate the production of transportation fuel via a combined biomass gasification (BG) and Fischer-Tropsch (FT) process. This review explains the basic background of the BG-FT process, including the gasification, gas cleaning, and FT processes. Numerous aspects of this process, such as the influence of the feedstock type and characteristics and the processing conditions, efficient process design, and FT-catalyst performance improvement, are reviewed based on laboratory-scale research reported in the literature. The tar removal process used to produce the synthesis gas satisfying the FT specification is also focused in this review. Moreover, the technical and economic prospects of the current BG-FT process to produce transportation fuels are reviewed and compared. Finally, trends in the future research of the BG-FT process are examined.
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Sustainability analysis of the bio-dimethyl ether (bio-DME) production via integrated biomass gasification and direct DME Synthesis Process
(2023-05-01)
Im-orb, Karittha
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Piroonlerkgul, Pakorn
The sustainability analysis based on life cycle assessment (LCA) of bio-dimethyl ether (bio-DME) production via an integrated biomass gasification and direct DME synthesis (IBG-DME) process, using oil palm residue as feedstock, was performed. The IBG-DME process was simulated in Aspen plus. Operating at selected condition, the IBG-DME was an exothermic process, whereas for 1 kg h−1 of oil palm trunk, bio-DME of 0.3456 kg h−1 and bio-methanol of 0.015 kg h−1 were produced as main product and by product, respectively, with energy efficiency at 59.5%. The energy consumption increased as gasifying temperature increased and reached thermal self-sufficient condition at approximately 890 °C but the CO<inf>2</inf> emission showed opposite trend. LCA result indicated that the carbon footprint of each unit operation relied on the energy consumption. For biomass gasification section, the global warming potential (GWP) accounted for approximately 91% of the total impact. The DME production section highly contributed toward the ozone depletion potential (ODP), eco-toxicity (ET), and human toxicity-non-carcinogenics (HTNC) whereas the syngas cleaning and conditioning section highly contributed toward GWP, human toxicity potential by ingestion (HTPI), and aquatic toxicity potential (ATP). The endpoint impact on the ecosystem were higher than the human health for all process sections.
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Process and sustainability analyses of the integrated biomass pyrolysis, gasification, and methanol synthesis process for methanol production
(2020-02-15)
Im-orb, Karittha
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Arpornwichanop, Amornchai
Technical and sustainability analyses of the methanol production via the integrated biomass pyrolysis, gasification, and methanol synthesis (IBPGM) process using rice straw as feedstock, are performed. The utilization of emitted CO<inf>2</inf> by recycling to a gasifier as a gasifying agent is investigated for technical and environmental reasons. The effects of CO<inf>2</inf> recirculation on the product distribution and energy consumption of the IBPGM process are examined. The production rate of methanol is improved with the increased CO<inf>2</inf> recycle fraction, while that of bio-oil does not change. The IBPGM is a highly exothermic process, with the largest energy-releasing unit being the methanol reactor. The energy consumption at the gasifier exhibits the same trend and thermal self-sufficiency is consequently achieved when the recycle fraction is raised to 0.76. Environmental assessment using a life cycle analysis tool reveals that the energy management of methanol synthesis unit and syngas processor needs to be improved as they highly contribute toward the carbon footprint and potential environmental impact. The technical and environmental factors of the IBPGM process are evaluated by the analysis hierarchy process, calculated by a multi-criteria decision analysis method. The IBPGM process with the CO<inf>2</inf> recycle fraction of 0.2 offers the best performance. Under this condition, the methanol and bio-oil production rates of 0.23 and 0.09 kmol h−1, respectively, and the energy efficiency of 60.7% can be achieved, based on the biomass feed rate of 1 kmol h−1.
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Bio-methanol production from oil palm residues: A thermodynamic analysis
(2020-12-15)
Im-orb, Karittha
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Phan, Anh N.
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Arpornwichanop, Amornchai
The thermodynamic analysis of bio-methanol production from oil palm residues was performed using a process model developed in Aspen Plus. Among the different types of oil palm residues, i.e., trunk, frond, and empty fruit bunch, the trunk residue offers the highest synthesis gas (syngas) (H<inf>2</inf> and CO) yields via the gasification process; therefore, it was selected as the biomass model compound. The effect of gasification operating conditions on the syngas composition, yield, bio-methanol production, energy consumption, and exergy performance was examined. The yield of syngas increased with increasing gasifying temperature, whereas that of bio-methanol exhibited the opposite trend due to the decrease in H<inf>2</inf> concentration of the syngas. The gasifier was an important unit for enhancing the exergy efficiency of the system, which was decreased when the equivalent ratio (ER) and gasifying temperature increased. Recirculating pressure swing adsorption offgas to the gasifier did not benefit bio-methanol production, nor did it improve energy and exergy performance. The maximum yield of bio-methanol was achieved by a once-through process that maintained the gasifying temperature at 750 °C and ER at 0.25. Under these conditions, the maximum energy and exergy efficiencies were 38.57 and 25.44%, respectively.
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Comparative techno-economic and energy analyses of integrated biorefinery processes of furfural and 5-hydroxymethylfurfural from biomass residue
(2023-04-01)
Wiranarongkorn, K.
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Im-orb, K.
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Patcharavorachot, Y.
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Maréchal, F.
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Arpornwichanop, A.
For efficient feedstock and energy utilization, integrated biorefinery processes are applied to furfural production from bagasse to convert furfural residue into 5-hydroxymethylfurfural (HMF)—an important intermediate building block for the production of various biochemicals. Here, a techno-economic analysis of the integrated processes of furfural and HMF production combined with electricity generation under different scenarios was performed to identify the most suitable process design. Simulations revealed that using the whole bagasse in the biorefinery plant and recycling 50% waste from the HMF production to recover unreacted sugar (scenario 2) achieved the maximum furfural and HMF production with minimum CO<inf>2</inf> emission, compared with integrated processes without sugar recycling (scenario 1), with 80% (scenario 3) and 60% biomass (scenario 4) bypassed to the biorefinery, and with a standalone combined heat and power system (scenario 5). Moreover, heat integration improved the efficiency of biorefinery plant (scenario 2), with an energy recovery potential of 71%, leading to the maximum profit at 11% internal rate of return. However, the high operating cost associated with the requirement of solvents and catalysts for HMF production represents the largest cost distribution in the proposed integrated processes. Sensitivity analysis revealed that solvent cost was the most important parameter for economic benefit. In addition, improving technological efficiency in the pretreatment and HMF production phases can enhance product yield, thereby benefiting the profitability of this process.

Imorb, Karittha

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