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    Frictional heat-assisted performance enhancement in dynamic Schottky contact of Al/Ag2Se-based tribovoltaic nanogenerator
    (2025-01-01)
    Worathat, Supakarn
    ;
    Pharino, Utchawadee
    ;
    Pakawanit, Phakkhananan
    ;
    Rattanachata, Arunothai
    ;
    The tribovoltaic nanogenerator (TVNG) has evolved in recent years as a novel type of nanogenerator designed to address the limitations of the standard triboelectric nanogenerator in terms of output signal and charge generation. Besides the outstanding characteristics, the tribovoltaic effect can also well be coupled with another effect to further boost the output performance. In this work, we proposed firstly a frictional heat-assisted performance enhancement in dynamic Schottky contact from the rubbing between n-type silver selenide (Ag<inf>2</inf>Se) and aluminum. The chemical composition and physical characteristics of the Ag<inf>2</inf>Se ceramic were analyzed using X-ray diffraction, scanning electron microscopy, and Synchrotron X-ray tomography techniques. UV–Vis spectroscopy and UPS were also utilized in order to validate the semiconducting property of the n-type Ag<inf>2</inf>Se ceramic. Moreover, the presence of the Schottky junction was demonstrated through the analysis of the current-bias voltage characteristic curve of the Ag<inf>2</inf>Se/aluminum (Al) contact under varying stress and temperature conditions. The built-in electric field plays a crucial part in the tribovoltaic effect by efficiently transferring the excited carriers to an external load through sliding contact between Ag<inf>2</inf>Se and Al. Demonstrating the synergy between tribovoltaic and thermoelectric effects becomes achievable through the excellent thermoelectric property of Ag<inf>2</inf>Se. Herein, the proposed TVNG generated a peak output voltage and current of around 0.7 V and 24.8 nA, respectively, achieving a maximum output power of 12.6 nW at a load resistance of 10 kΩ. The influence of frictional heat on the output performance of the proposed TVNG was well demonstrated by the thermal-induced voltage and enhanced electrical output from continuous sliding. The concepts given in this study establish the basis for the progress of effective energy collection employing semiconducting materials and the advancement of flexible harvesting and sensing device development in the future.
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    Item type:Publication,
    Acidic dynamics: Unveiling mechanistic insights for improved performance in chitosan triboelectric nanogenerators
    (2024-07-01)
    Charoonsuk, Thitirat
    ;
    Ukasi, Sirinya
    ;
    Mokthaisong, Panadta
    ;
    Khuntakaew, Pawita
    ;
    Hajra, Sugato
    In recent years, there has been a surge in interest surrounding the development of chitosan (CS)-based triboelectric nanogenerators (TENG) for powering attachable/portable devices. Despite numerous strategies aimed at enhancing their efficiency, the selection of acid solvent has remained largely unexplored. In this study, various acids, including acetic (CH<inf>3</inf>COOH), succinic (C<inf>4</inf>H<inf>6</inf>O<inf>4</inf>), and citric (C<inf>6</inf>H<inf>8</inf>O<inf>7</inf>) acids, were investigated for their impact on mechanical and electrical output signals. Remarkably, the choice and concentration of acid were found to significantly influence performance. Specifically, employing citric acid rendered the CS solid film more pliable and yielded the highest output signal at optimal concentration levels. Under optimized conditions, the CS-TENG exhibited an open-circuit voltage output (V<inf>OC</inf>) of 157 V and short-circuit current output (I<inf>SC</inf>) of 53 µA—more than triple that of pristine CS-TENG. Mechanistic insights into electrical generation have been elucidated, underscoring the importance of solvent selection in CS TENG fabrication. These findings underscore the potential for tailored acid solvent selection to advance specialized applications in the field.
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