Suteewong, Teeraporn

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Suteewong, Teeraporn
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teeraporn.su@kmitl.ac.th

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    A concise review on design and control of structured natural rubber latex particles as engineering nanocomposites
    (2021-10-05)
    Wichaita, Waraporn
    ;
    Promlok, Duangkamol
    ;
    Sudjaipraparat, Narissara
    ;
    Sripraphot, Supang
    ;
    Suteewong, Teeraporn
    In this article, we review the modification of natural rubber (NR) latex into the engineered particles for make use of them in functional nanocomposites. The review focuses on tuning nano-/microstructure and/or composition of NR latex particles by means of surface chemical functionalization, structural modification and incorporation of inorganic nanoparticles (NPs). Due to their polydispersity in size and non-spherical shape with complicated indigenous stabilizers, i.e., proteins and lipids, we first describe the fundamental and common methods for the modification of synthetic polymer latex which become a practical guideline for engineering of NR particles to a variety of designs. Subsequently, the examples of successfully modified NR latex and the involved parameters in the preparation are discussed. The different nature and properties of the modified NR latex compared to the synthetic latex are then depicted. Finally, specific examples of these systems used in a range of applications including nanofillers, controlled releasing materials, textiles, electronics and coatings are demonstrated. The research on modification of NR latex particles would be beneficial to the field of materials science and engineering for the valorization of naturally abundant colloidal polymer to the advanced functional materials in the broader utilization/commercialization in the future.
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    Fabrication of hollow magnetic polyaniline particles via in-situ polymerization in one-pot for UV–Vis-NIR and EMI applications
    (2024-01-01)
    Promlok, Duangkamol
    ;
    Wichaita, Waraporn
    ;
    Phongtamrug, Suttinun
    ;
    Kaewsaneha, Chariya
    ;
    Sreearunothai, Paiboon
    The concern on the adverse impacts of electromagnetic (EM) pollution has continuously increased. Instead of using heavy metal sheet, this work aims to develop magnetic polymeric particles, that can easily be incorporated in coatings, for EM/ultraviolet-visible-near infrared (UV–Vis-NIR) shielding. By carefully design structure and key components, hollow magnetic (HoM) polyaniline (PANI) particles possessing a void encircled with magnetic nanoparticles dispersed in PANI semi-conductive shell were fabricated via the oxidative polymerization in emulsion system. By using ethyl benzene as a soft template and different surfactive dopants, i.e., sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, and poly(sodium 4-styrenesulfonate) (PSS), the HoM-PANI particles (0.5–2 μm) with well-defined hollow structure, high magnetic loading (17–21%wt), and superparamagnetic properties were obtained. The particle size distribution, and magnetic loading were slightly affected by the reaction temperature, whereas molecular weight (M<inf>w</inf>) of the localized dopant considerably influenced on the levels of interparticle connectivity, and hence, the conductivity could be tailored. The water dispersible HoM-PANI particles could form opaque coating, and free-standing film. PSS with M<inf>w</inf> of 70 K and 1 M yielded the larger HoM-PANI particles and more opaque films than small dopant molecules. Void size was the determining effect on excellent opacity of the coating containing HoM-PANI dispersed in poly(vinyl alcohol) matrix against UV–Vis-NIR, and EM radiation. The ability to tune their optical properties, and electrical conductivity accomplished by designing the particle nanostructure, and doping/de-doping by localized dopants enables them the promising candidates for functional paint, and film for irradiation protection.
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    Item type:Publication,
    Hollow core-shell particles via NR latex seeded emulsion polymerization
    (2016-09-02)
    Wichaita, Waraporn
    ;
    Polpanich, Duangporn
    ;
    Suteewong, Teeraporn
    ;
    Tangboriboonrat, Pramuan
    Natural rubber (NR)-based hollow latex (HL) particles have been prepared by seeded emulsion polymerization of methyl methacrylate/divinyl benzene/acrylic acid (MMA/DVB/AA) monomers on NR seed. By using tert-butyl hydroperoxide/tetraethylene pentamine (t-BuHP/TEPA) as a redox initiator, the locus of polymerization was localized at the surface of the NR particle. After swelling with monomers, DVB in NR particle gradually moved outward to compensate the co-polymerization. Phase separation between the NR seed and the polymeric shell occurred and a void was subsequently formed at a MMA/DVB molar ratio of 2.7/1. The void cavity was enlarged when the monomer to seed (M/S) weight ratio was increased to 4/1. Without the necessity of any residual core removal, polydisperse NR-based hollow nanocomposites (298 ± 58 nm) possessing NR-P(MMA/DVB/AA) double-layered shell and a single void (155 ± 37 nm) were obtained. SEM images revealed an increase in surface roughness of the HL particle with increasing M/S weight ratios. The large specific surface area of these NR-based hollow nanocomposites (114.6 m<sup>2</sup>/g) with a 3.5 nm pore diameter indicates that the polymeric shell is mesoporous. The presence of carboxyl groups, as indicated by negative zeta potentials, can further facilitate surface functionalization. The large void cavity of these NR-based HL particles makes them particularly suited as delivery vehicle systems.