Highly stable Pd<sup>2+</sup> species anchoring on ethylenediamine-grafted-MIL-101(Cr) as a robust oxidation catalyst

Nuttapong Makmeesub; Chonlada Ritvirulh; Kittisak Choojun; Suchinda Sattayaporn; Daniel E. Resasco; Tawan Sooknoi

doi:10.1039/d1cy01932e

Highly stable Pd<sup>2+</sup> species anchoring on ethylenediamine-grafted-MIL-101(Cr) as a robust oxidation catalyst

Date

2022-1-1

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Catalysis Science & Technology

Abstract

The strong interaction between Pd 2+ and ethylenediamine (en), within the confinement of MIL-101(Cr), effectively prevented the reduction of Pd 2+ by the feed and minimized leaching of the active Pd 2+ species under oxidizing and acidic conditions.

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Metal-Organic Frameworks: Synthesis and Applications, Catalytic Processes in Materials Science, Chemical Synthesis and Reactions

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https://dspace.kmitl.ac.th/handle/123456789/16346

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Highly stable Pd<sup>2+</sup> species anchoring on ethylenediamine-grafted-MIL-101(Cr) as a robust oxidation catalyst

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