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Physical properties of V-doped TiO2 nanoparticles synthesized by sonochemical-assisted process
Author(s)
Date Issued
May 1, 2013
Type
Conference Paper
Abstract
V-doped TiO2 nanoparticles were synthesized by sonochemical process using titanium isopropoxide as a titanium source, vanadyl acetylacetonate as a dopant source. Sonication was conducted using sonic horn operated at 20 kHz for 20 min until the completely precipitated product was reached. The as-synthesized precipitates with various vanadium dopant (1-5 mol %) were calcined at 500-1000 °C for 4 h. The relevant physical properties of the nanoparticles were characterized by X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and transmission electron microscope (TEM). The anatase phase TiO2 nanoparticles can be synthesized by sonochemical process. Post calcinations process results in the anatase-to-rutile phase transformation and the enhancement in crystallinity with increasing temperature. The results also indicate good incorporation of V ions in TiO2 lattices and significant effect of V dopant on alternation of interplanar spacing of TiO 2. © 2012 Elsevier Ltd and Techna Group S.r.l.
Citation
Ceramics International, 39(SUPPL.1), S389-S393, 2013