KMITL
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Item type:Publication, Phase formation polycrystalline vanadium oxide via thermal annealing process under controlled nitrogen pressure(2017-10-20) ;Jessadaluk, S.; ; ; This article provides an approach to improve and control crystal phases of the sputtering vanadium oxide (V<inf>x</inf>O<inf>y</inf>) thin films by post-thermal annealing process. Usually, as-deposited V<inf>x</inf>O<inf>y</inf> thin films at room temperature are amorphous phase: post-thermal annealing processes (400 °C, 2 hrs) under the various nitrogen (N<inf>2</inf>) pressures are applied to improve and control the crystal phase of V<inf>x</inf>O<inf>y</inf> thin films. The crystallinity of V<inf>x</inf>O<inf>y</inf> thin films changes from amorphous to α-V<inf>2</inf>O<inf>5</inf> phase or V<inf>9</inf>O<inf>17</inf> polycrystalline, which depend on the pressure of N<inf>2</inf> carrier during annealing process. Moreover, the electrical resistivity of the V<inf>x</inf>O<inf>y</inf> thin films decrease from 10<sup>5</sup> Ω cm (amorphous) to 6×10<sup>-1</sup> Ω cm (V<inf>9</inf>O<inf>17</inf>). Base on the results, our study show a simply method to improve and control phase formation of V<inf>x</inf>O<inf>y</inf> thin films<inf>.</inf>1 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Control the crystal growth of Al-doped ZnO thin film prepared by pulsed laser deposition and the influences on its optical and electrical properties(2017-10-20); ;Jessadaluk, S.; ; In this work, highly transparent and highly conductive thin films of Al-doped ZnO (AZO) are achieved by pulsed laser deposition (PLD). By changing substrate temperature in the range of room temperature to 500°C during the deposition process, the preferential growth direction of AZO crystal is controlled and, therefore, the surface morphology, optical and electrical properties of AZO thin films are able to be manipulated. X-ray diffractograms as a function of the substrate temperature clearly illustrate the ability to control the preferential growth direction of AZO. At the low substrate temperature, the growth along [002] direction corresponding to c-axis of hexagonal ZnO is only observed. By elevating the substrate temperature, not only crystallinity of AZO thin film is further improved but also the competition of crystal growth along the [002], [001] and [101] directions are occurred due to the increase of total energy and surface mobility of cluster/atom. The AZO films obtained by all preparation conditions exhibit an n-type semiconducting characteristics, furthermore, the carrier concentration and the carrier mobility of AZO thin films can be optimized to reach 4.10×10<sup>20</sup> cm<sup>-3</sup> and 7.53 cm<sup>2</sup>/Vs, respectively. The excellences in both carrier concentration and mobility of AZO thin film lead to very low resistivity of 2.08×10<sup>-3</sup> cm. In addition, the wide optical band gap of ∼3.50 eV together with the high transparency over 90% in visible region is obtained from the AZO thin films. The exceptional optical and electrical properties of AZO thin film demonstrate that such material has enough potential to become a promising candidate using in optoelectronic applications.4 - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Optical band engineering of metal-oxynitride based on tantalum oxide thin film fabricated via reactive gas-timing RF magnetron sputtering(2016-11-25); ;Jessadaluk, S. ;Chananonnawathorn, C. ;Vuttivong, S.Lertvanithphol, T.In this paper, we demonstrate a novel technique, as called reactive gas-timing (RGT) RF magnetron sputtering, to control and design an optical band engineering of TaON thin films without an external heating substrate temperature and post annealing treatment process. The influence of the oxygen intervals ranged from 5 to 60 s on deposition rate, chemical composition and optical properties of TaON thin films were investigated. The chemical composition was characterized by auger electron spectroscopy (AES). The optical properties were determined by UV–Vis spectrophotometer and spectroscopic ellipsometry. The nitrogen atomic concentration of the TaON thin films deposited by RGT decreased when the oxygen gas-timing intervals increased. In addition, the RGT sputtered TaON films could be demonstrated band gaps engineering from 1.90 to 2.15 eV.1
