Maluangnont, Tosapol
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Maluangnont, Tosapol
Alternative Name
Maluangnont, T.
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Email
tosapol.ma@kmitl.ac.th
14 results
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Item type:Publication, Tailoring charge affinity, dielectric property, and band gap of bacterial cellulose paper by multifunctional Ti2NbO7 nanosheets for improving triboelectric nanogenerator performance(2023-02-01) ;Sriphan, Saichon ;Pharino, Utchawadee ;Charoonsuk, Thitirat ;Pulphol, PhierayaPakawanit, PhakkhanananTransparent, flexible, and high-performance triboelectric nanogenerator (TENG) from nature-derived materials are required for sustainable society development. However, low triboelectricity from natural material is generally observed. Tunable electronic band diagram (EBD) through facile manipulation is one of the efficient methods to promote the TENG output, requiring fundamental, in depth understanding. Herein, we employed the high quality, single crystal-like Ti<inf>2</inf>NbO<inf>7</inf> nanosheets (NSs) with dual dielectric and semiconducting properties as filler for bacterial cellulose (BC)-based TENG. Several techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), ultraviolet—visible (UV—vis) absorption, energy dispersive X-ray spectroscopy (EDS), and synchrotron radiation X-ray tomographic microscopy (SRXTM) were applied to characterize the long-range structure, microstructure, optical properties, elemental composition, and three-dimensional (3D) distribution of components in the composites. The semi-transparent and flexible 5 vol.% Ti<inf>2</inf>NbO<inf>7</inf> NSs/BC preserved the integrity of cellulose, contained well-dispersed nanosheets, reduced optical band gap (4.20 vs. 5.75 eV for BC), and increased surface roughness. The dielectric permittivity and conductivity increased with nanosheets content. Adding negatively-charged Ti<inf>2</inf>NbO<inf>7</inf> NSs could regulate the charge affinity of BC composite via shifting of Fermi energy over that of Al. It is found that adding 5 vol.% NSs into the BC film improved electrical outputs (~ 36 V and ~ 8.8 µA), which are 2–4 times higher than that of pure BC, even when paired with Al which lies adjacent in triboelectric series. Our work demonstrated the method to enhance BC-based TENG performance through EBD regulation using multifunctional Ti<inf>2</inf>NbO<inf>7</inf> NSs. [Figure not available: see fulltext.] - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Highly Flexible Tribovoltaic Nanogenerator Based-on P-N Junction Interface: Comparative Study on Output Dependency Dominated by Photovoltaic Effect in Freestanding-Mode(2023-10-18) ;Sriphan, Saichon ;Worathat, Supakarn ;Pharino, Utchawadee ;Chanlek, NarongPakawanit, PhakkhanananThe emergence of tribovoltaic nanogenerators (TVNGs) paves the way for developing a new kind of semiconductor-based energy harvester that overcomes the restriction of low output current in a conventional approach. The traditional TVNG generally depends on the frictional pair between two rigid semiconductors (or metal-semiconductor), limiting the practicability of flexible and portable electronics. Recent developments require the fundamental understanding of charge generation in diverse operating modes and structures. Here, a flexible TVNG based on the p-Cu<inf>2</inf>O/n-g-C<inf>3</inf>N<inf>4</inf> interface is presented. Operating in a freestanding mode, the proposed TVNG can generate a stable signal in any optical conditions including UV illumination, dark, and ambient. Under UV illumination, the electrical outputs of the TVNG reach 0.43 V and 2.1 µA cm<sup>−2</sup>, which are significantly larger than those obtained from dark and ambient conditions. The results demonstrate the coupling effect of three phenomena: tribovoltaic, photovoltaic, and triboelectric effects, and the unique mechanism to the observed signal is proposed. Additionally, the TVNG shows the practical feasibility of energy harvesting with capacitor charging and charge-boosting circuits. This study showcases the unique concept with potential for developing a novel flexible nanogenerator in many aspects, including material, structure, and fundamental mechanism. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, AC Electrical Properties of a NiFe-Layered Double Hydroxide with an Exceptionally Low Charge Density(2025-05-08); ;Sriphan, Saichon ;Chaithaweep, Kanokwan; Wijitwongwan, Rattanawadee PloySingle-phase NiFe-layered double hydroxides (LDHs) with low and high charge densities [CD, 0.85 vs 3.23 nm<sup>-2</sup>; Fe<sup>III</sup>/(Ni<sup>II</sup> + Fe<sup>III</sup>) = 0.05 and 0.25] were successfully prepared via urea-assisted coprecipitation in aqueous glycerol under hydrothermal conditions. The low-CD NiFe-LDH showed decreased apparent activation energies of water evaporation and of glycerol thermal decomposition, suggesting diminished intercalate/layer interactions relative to the high-CD one. The alternating current properties of the two samples were investigated on frequency and temperature domains by several formalisms that highlight distinct electrical components. We found that the low-CD NiFe-LDH exhibited smaller static dielectric permittivity and slower relaxation time, and it was less conducting than the high-CD analog. Complex plane analyses revealed the temperature dependence of resistance and capacitance at grain and grain boundary, varying by 7-10 orders of magnitude due to water loss and glycerol loss (∼9.5 and 11.3 wt %, respectively). Our work provides insights into intercalate dynamics in a low charge density LDH, which is difficult to obtain so far, from ambient to elevated temperatures (RT-250 °C) prior to decarbonation and layer collapse. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, AC Conductivity and dielectric properties of lepidocrocite-type alkali titanate tunable by interlayer cation and intralayer metal(2020-11-02) ;Charoonsuk, Thitirat ;Sriphan, Saichon ;Pulphol, Phieraya; The lepidocrocite-type layered alkali titanate AxMyTi2-yO4 has diverse chemical compositions with variation in charge per formula unit x, the interlayer cation A+, and the intralayer metal M. Despite this multivariable nature, the composition dependence of physical properties is not well explored. We report herein the AC conductivity and the complementary dielectric properties of Cs0.7M0.35Ti1.65O4, K0.8M0.4Ti1.6O4 (M = Zn, Ni), and the mixed-interlayer ion Cs0.6K0.1Zn0.35Ti1.65O4. For Cs0.7Zn0.35Ti1.65O4, the total AC conductivity is ~7 × 10-8 to 2 × 10-6 S·cm-1 at 200-350 °C, associating with an activation energy Ea ∼865 meV. Meanwhile, the conductivity of K0.8Zn0.4Ti1.6O4 is higher by 1 order of magnitude at much lower temperature (25-150 °C) and a smaller Ea ∼250 meV. This difference originates from the compositional robustness of the cesium-containing samples, contrasting with the sintering-induced changes in the potassium analogues. For the latter, the loss of the interlayer K+ ion results in (i) generation of carriers due to charge compensation, (ii) reduction of sheet charge density and weakening of electrostatic attraction, and (iii) widening of the interlayer distance, all contributing to a lower Ea in K0.8M0.4Ti1.6O4. The angular frequency dependence of conductivity, dielectric permittivity (up to a colossal value of 109), and dielectric loss follows the universal power law. Our work demonstrates the potential of simple compositional variation for electrical properties tuning, prompting a more in-depth investigation covering a wider range of possible candidates of x, A+, and M in lepidocrocite titanate. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effect of Adsorbed Water and Temperature on the Universal Power Law Behavior of Lepidocrocite-Type Alkali Titanate Ceramics(2021-06-17) ;Sriphan, Saichon ;Pulphol, Phieraya ;Charoonsuk, Thitirat; The ubiquitous (re)adsorption of atmospheric water by functional ceramics leads to some applications such as humidity sensing; at the same time, this phenomenon complicates the understanding of the nature of original conducting species. We presented herein the effects of adsorbed water on the electrical properties and charge transport of K0.8Zn0.4Ti1.6O4, Cs0.7Zn0.35Ti1.65O4, and Cs0.6K0.1Zn0.35Ti1.65O4 lepidocrocite-type alkali titanate ceramics. A small amount of atmospheric water (0.02-0.33 mol/mol) is merely adsorbed on the external surface but not intercalated into the interlayer space. In temperature scan experiments, water sorption leads to the dielectric permittivity/loss hysteresis loops, where the values upon cooling are unusually larger than those upon heating. In frequency scan experiments, multiple frequency- and temperature-dependent anomalies are detected. The AC conductivity was fitted to the Jonscher universal power law response (σ′AC = σDC + Aωs) from 101 to 106 Hz and 400-25 °C. We observed an uncommon U-shaped A(T) but an inverted U-shaped s(T), regardless of the interlayer ion, charge per formula unit, or pellet density. These plots allow a qualitative description of (i) the apparent activation energy, (ii) the effective dimension of the conduction pathway, and (iii) the charge carrier concentration, all as a function of the temperature under the influence of atmospheric water. Our physical interpretation is potentially applicable to other systems, providing insights into the (unintentional) water-induced conductions and complementing rigorous but time-consuming investigations by controlled humidity experiments. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, High-Performance Droplet-Based Triboelectric Nanogenerators: A Comparison of Device Configuration and Operating Parameters(2025-05-06) ;Chaithaweep, Kanokwan ;Pharino, Utchawadee; ;Hajra, SugatoKim, Hoe JoonDroplet-based electricity generators (DEGs) harness liquid-solid electrification to convert water droplets impacts into electrical energy. This study systematically examines how droplet height, droplet volume, flow rate, and substrate tilt angle influence DEG performance using polytetrafluoroethylene (PTFE) as a triboelectric layer and deionized water. Three electrode designs (double, top, bottom) are evaluated, revealing that the double-electrode configuration delivers the highest output. This enhanced performance arises from synergistic droplet motion, electrical double-layer formation, and charge discharge, as validated by an equivalent circuit model. By varying droplet heights from 1–20 cm, volumes of 7.7–50 µL, flow rates of 50–300 drops/min, and tilt angles of 0–90°, an optimized setup yields −70 V and 22 mA, translating to a power density of 0.28 µW cm<sup>−2</sup>. High-speed imaging correlates these outputs with droplet impact dynamics and the resulting charge transfer. Additionally, the optimized DEG can power small electronic devices, charge capacitors, and monitor artificial acid rain in real-time, displaying distinct electrical signals compared to typical rainwater. These findings underscore the potential of DEGs as renewable energy harvesters and smart environmental sensors, paving the way for advanced on-demand power generation in diverse settings. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, High-Performance Hybridized Composited-Based Piezoelectric and Triboelectric Nanogenerators Based on BaTiO3/PDMS Composite Film Modified with Ti0.8O2 Nanosheets and Silver Nanopowders Cofillers(2019-05-28) ;Sriphan, Saichon ;Charoonsuk, Thitirat; In order to commercialize the rapidly developing technology of energy harvesters, the following devices need to be developed further for enhancing output performance, flexibility, scalability, facile fabrication, and cheaper price. The composite-based triboelectric nanogenerator (CTENG), which contains the above properties, is a promising technology that has attracted special interest for a decade. Focus has been placed on the hybrid concept between the composite-based piezoelectric nanogenerator (CPENG) and CTENG in order to enhance CTENG efficiency. This study presented a high-performance hybridized CPENG and CTENG device, which operated from the composite film of Ti<inf>0.8</inf>O<inf>2</inf> nanosheets (Ti NSs)/silver nanoparticles (Ag NPs) co-doped BaTiO<inf>3</inf> nanopowders (BT NPOs) inside the polydimethylsiloxane (PDMS) host. The 0.3 vol % of Ti NSs and 1.5 vol % of Ag NPs exhibited the optimum harvesting performance in all compositions, with an output voltage and current density reaching approximately 150 V and 0.32 μA/cm<sup>2</sup>, respectively. Their harvesting performance was approximately 60 and 32 times higher than that of the CPENG constructed from pure PDMS. In addition, practical demonstration of the proposed device was investigated. The hybridized CPENG and CTENG device could operate in a long-term cyclic operation, charge the capacitor for storing energy, and also drive LEDs to brighten. This work suggested facile device fabrication and made a guideline to develop high-performance nanogenerators, which is crucial for device development and practical usage in the future. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Kinetic analysis of liquid–solid contact electrification: Using adsorption models as mechanistic probes for hybrid EDL behavior(2026-08-01) ;Chaithaweep, Kanokwan ;Pharino, Utchawadee; ;Sriphan, SaichonCharoonsuk, ThitiratLiquid–solid interfaces are central to technologies ranging from energy storage to triboelectric nanogenerators (TENGs). Whereas classical electric double layer (EDL) theory describes these interfaces mainly in terms of electrostatic ion adsorption, hybrid EDL concepts suggest that interfacial electron transfer may also contribute importantly to charge generation. However, the hybrid EDL model has so far been discussed primarily at a qualitative level or through complex theoretical and computational treatments, and a simple, experimentally accessible macroscopic kinetic handle that can discriminate, in operando, between adsorption‑dominated and ET‑influenced regimes remains lacking. By analyzing high-resolution charging dynamics over systematically varied H₂SO₄ and HNO₃ concentrations, a clear concentration-dependent kinetic transition is identified. At low ionic strengths, the charging process is described more effectively by pseudo-second-order (PSO) kinetics, consistent with a reaction-influenced interfacial step, whereas at higher concentrations the system becomes pseudo-first-order (PFO) dominated, consistent with transport- and ion-screening-controlled behavior. Although previous studies have provided compelling theoretical and spectroscopic evidence that interfacial electron transfer contributes to liquid–solid contact electrification in TENGs, these mechanisms have rarely been examined through such simple macroscopic kinetic formalisms. In this work, classical adsorption kinetic models are used as operational probes for distinguishing electron-transfer-influenced regimes from ion-transport-dominated regimes at PTFE/liquid interfaces. The PSO-to-PFO crossover reported here is interpreted within the hybrid EDL framework as a kinetic marker of a transition from an electron-transfer-influenced charging regime at low concentration to an ion-transport- and screening-dominated regime at high concentration, thereby demonstrating how adsorption kinetics can serve as a practical diagnostic language for liquid–solid triboelectric systems. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Piezoelectric Energy Harvesting for Low-Power Smart Electronics(2023-01-01) ;Sriphan, Saichon ;Charoonsuk, Thitirat; In recent years, significant progress regarding energy harvesting has been made, owing to the need to replace conventional energy sources with alternative, green, and sustainable ones. Among them, mechanical energy harvesting is a promising strategy with outstanding characteristics of high conversion efficiency, facile fabrication process, simple structure, flexible selection of materials, and the ability to capture energy independent of season. Nowadays, the piezoelectric mechanism has gained attention from the research community as a prominent mechanical energy harvesting method. Diverse technologies in harvesting and sensing schemes have been innovatively developed alongside explorations of novel piezoelectric materials and the establishment of theoretical foundations. This article comprehensively reviews piezoelectric energy harvesting from the research background to its significance. The operation mechanisms of a piezoelectric nanogenerator (PENG) in various modes, including the theoretical principle of piezoelectricity, are discussed. Three generations of piezoelectric material development are explained, including structural designs of PENG for specific applications. Finally, highlighted applications of PENG in diverse fields such as energy harvesting and sensing, biomedical electronics, and novel intelligent sensing technologies, have been reviewed. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Multifunctional Nanomaterials Modification of Cellulose Paper for Efficient Triboelectric Nanogenerators(2020-05-01) ;Sriphan, Saichon ;Charoonsuk, Thitirat; ;Pakawanit, PhakkhanananRojviriya, CatleyaThere is a need to develop inexpensive, lightweight, and flexible high-performance triboelectric nanogenerators (TENGs) from renewable resources. Here, a multifunctional cellulose filter paper (CFP)-based TENG consisting of dielectric Ti<inf>0.8</inf>O<inf>2</inf> nanosheets (Ti<inf>0.8</inf>O<inf>2</inf> NSs) and conducting Ag nanoparticles (Ag NPs) is prepared by a simple dip coating method. The incorporation of dielectric Ti<inf>0.8</inf>O<inf>2</inf> NSs onto the CFP significantly improves charge generation, while the inclusion of Ag NPs provides an electrically conductive path for charge transportation. The presence of these fillers can be deduced from XRD, SEM, EDS, X-ray photoelectron spectroscopy, and Raman spectroscopy. Their distribution is visualized in 3D by synchrotron radiation X-ray tomography. The present CFP-based TENG provides an output voltage and current density of ≈42 V and ≈1 µA cm<sup>−2</sup>, respectively with the power density of ≈25 µW cm<sup>−2</sup>. It is capable of lighting up 40 light-emitting diode bulbs and charging a 0.22 µF capacitor to 8 V in only 5 s. The developed TENG is also capable of detecting simple human motions, i.e., finger tapping, finger rubbing, and foot trampling. This work offers a facile design of low cost yet efficient paper-based TENG by dual modification with multifunctional nanomaterials, and also demonstrates its use as a feasible power source that not only drives small electronics, but also scavenges energy from human actions.
