Srirussamee, Kasama
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Item type:Publication, Microstructure and mechanical properties of Ti-Zr alloys fabricated by two-step spark plasma sintering from TiH2 and ZrH2 powders(2023-01-01) ;Banjongaxsorn, Kunpot ;Khantachawana, Anak ;Watanabe, Chihiro; Kondoh, KatsuyoshiTi is well-known for its high strength-to-weight ratio and biocompatibility. It can be alloyed with Zr to improve mechanical properties. Currently, Ti-Zr alloys can be fabricated by powder metallurgy using Ti and Zr powders, although high oxidation reactivity and cost could still be an issue. In this study, premixed TiH<inf>2</inf> and ZrH<inf>2</inf> powders were used to prepare Ti-Zr binary alloys with different Zr contents of 0–30 mass% ZrH<inf>2</inf> via dehydrogenation and sintering by spark plasma sintering (SPS) process. α-Ti and δ-TiH<inf>2</inf> phases coexisted in the sintered Ti-Zr alloys, and a characteristic lamellar microstructure was formed. The tensile strength of the Ti-Zr alloys increased with increasing Zr content due to the solid solution effect, grain refinement and the appearance of δ-TiH<inf>2</inf> phases, although the elongation was reduced. This study shows that the fabricated Ti-Zr alloys possess controllable mechanical properties, which can be beneficial for biomedical and other engineering applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Thermomechanical performance of the offset crankshaft heat engine driven by tinicu shape memory alloys(2021-01-01); ;Khantachawana, Anak ;Hok, BunhengPhukaoluan, AphinanGeothermal hot springs are among the alternative clean energy sources to the fossil fuels for mitigating the current global warming crisis. However, the accessible geothermal water at the surface was mostly at low temperature, which impairs the practicality of harvesting these energy. Shape memory alloys (SMAs), which deform through the increased temperature, were adapted into the rotating mechanism as the actuators with the aims to convert the low-temperature heat into the mechanical work. This study utilized the helical spring-shaped TiNiCu SMAs as the actuators for the offset crankshaft heat engine. Performance of this engine was evaluated using rope brake dynamometer, by which the rotational speed, torque, and power were measured at the water temperature from 55-85°C. The results show that the engine performance increased with increasing water temperature and was dependent on the crankshaft arrangement. The offset angle of 30° was found to be optimal in this study with maximum torque of more than 5.8 N∙m and maximum power of 3.9 W at 15.7 rpm when operating at water temperature of 85°C. This study shows that the heat engine driven by TiNiCu SMAs could harvest low-temperature energy from the geothermal hot springs with the maximum observable efficiency of around 1.4%. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Influence of mouthwash rinsing on the mechanical properties of polymeric ligature ties used for dental applications(2021-07-02) ;Phukaoluan, Aphinan ;Khantachawana, Anak ;Dechkunakorn, Surachai ;Anuwongnukroh, NiwatMouthwashes are used during dental treatments to mitigate the complications caused by poor oral hygiene. However, these solutions also affect the properties of dental appliances, including those used in orthodontics. This point has been investigated in this study focusing on the changes in mechanical properties of polymeric orthodontic ligature ties. Commercial ties from four brands were characterized in terms of their maximum forces and displacement, delivery forces, molecular structures, and microscopic morphology. These properties were compared against the ties, which were rinsed with commercial mouthwashes from three manufacturers. The results showed that mouthwash rinsing significantly reduced the maximum bearable forces of ligature ties by up to 73.1%, whereas the reduction in their maximum displacement was up to 74.5% across all tested brands. Significant changes in microscopic morphology of ligature ties were observed after mouthwash rinsing, but not their molecular structure. Furthermore, mouthwash rinsing also reduced the delivery forces from ligature ties by between 20.9 and 32.9% at their first deformation cycle. It can be concluded from this study that mouthwashes have significant impact on the mechanical properties of polymeric orthodontic ligature ties and could also potentially affect the overall efficacy of orthodontic and other dental treatments. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effect of Nb Content and water quenching on microstructure and mechanical properties of Ti-Nb alloys fabricated by spark plasma sintering(2022-01-01) ;Suesawadwanid, Nattawood ;Khantachawana, Anak; Kondoh, KatsuyoshiTitanium-niobium (Ti-Nb) alloys have been extensively studied for medical implants due to their advantageous mechanical properties and biocompatibility. However, the stress shielding effect remains a challenge. This research investigated the effects of Nb content and enhancement of α′′ formation on the mechanical properties of Ti-xNb alloys (x = 0, 5, 15 and 25%) fabricated by spark plasma sintering. Water quenching from the β phase induced α′′ phase formation in Ti-5Nb and Ti-15Nb samples, thereby reducing their Young’s modulus values but was not observed in commercially pure titanium (CP-Ti) and Ti-25Nb. Results showed that heat treatment with water quenching induced α′′ phase formation and can be used to tailor the properties of Ti-Nb alloys fabricated by SPS. This technique can also be used to enhance material ductility at high β-stabilizer content, as observed in Ti-25Nb samples. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, The Addition of Fluoride to the Eggshell-derived Hydroxyapatite: A Preliminary Study(2021-01-01) ;Uthayaphamornwat, Vilasinee ;Suksap, Arissara ;Khantachawana, Anak; Dental caries are one of the major oral health problems, which could be mitigated by addressing the dental defects. Hydroxyapatite (HA) is commonly used for tooth and bone replacement due toits similar properties as the native hard tissues. Natural sources with abundant availability, such as eggshells, could be used to synthesize HA. Moreover, with the presence of fluorine in HA, it was suggested that the performance of this material could be enhanced in terms of material stability and anti-caries properties. This preliminary study aims to compare two methods used to produce fluoride-added HA from eggshells, which are pH cycling and wet precipitation methods. The molecular structure, crystal structure, particle appearance and chemical compositions of the obtained samples were characterized. The results suggested that pH cycling has provided samples with higher fluorine content, more crystalline structure and less CO3than those obtained from wet precipitation method. Therefore, pH cycling method appears to be more suitable for further processing and characterization of the fluoride-added HA samples derived from eggshells. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Characterization of Fluoride-added Hydroxyapatite Derived from Eggshells for Dental Application(2023-01-01) ;Uthayaphamornwat, Vilasinee ;Khantachawana, Anak; ; Hydroxyapatite (HA) is one of the potential biomaterials used for treating dental defects. It can be incorporated with fluoride to enhance its anti-caries properties, though other properties could be dependent on processing technique. Hence, this study aims to characterize the influence of sintering on the properties of fluoride-added HA derived from eggshells. FTIR and XRD techniques are used to characterize the chemical and crystal structures of the samples, whilst dissolution test is carried out to characterize material degradation in the acidic environment. The results show that sintering increased the crystallinity in both HA and fluoride-add HA (F-HA) samples, which corresponds with the enhanced stability during the dissolution test. Moreover, it is also found that the addition of fluoride could further stabilize the material structure, though the impurities found in all the samples still need to be minimized. These findings suggest that sintering and fluoride addition could potentially enhance anti-caries properties of eggshell-derived HA, which could be beneficial for dental application in future subject to further process optimization and analysis. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Influence of the Oxide Film on the Performance and Corrosion Resistance of TiNiCu Shape Memory Alloys as the Heat Engine Actuator(2024-10-01) ;Phukaoluan, Aphinan; ;Khantachawana, Anak ;Chuchonak, MonthonShape memory alloys (SMAs) are utilized as an actuator for the heat engine to harvest energy from low-temperature geothermal sources, such as hot springs, which convert thermal energy into mechanical work. However, the alloy processing and engine design still require optimization to improve performance and durability. To discuss their potential as heat engine actuator, this study investigated the influence of oxide films on the TiNiCu SMAs in terms of surface and structural properties, recovery forces, and corrosion resistance. The results show that the surfaces of the etched samples were relatively coarser than those unetched with lower oxygen content. With the presence of oxide film, the Austenite Finish Temperature (Af) temperature of the unetched SMAs was lower with R-phase transformation. Also, it provided higher recovery force at above Af temperature (as high as 8.3 N at 70-mm displacement). Furthermore, the corrosion resistance of the unetched SMAs was higher than the etched samples, as analyzed by open-circuit potential and linear polarization in natural spring water at 70°C. These findings imply that the presence of oxide film could be beneficial for the SMAs when used as an actuator for heat engines, although it may require further study to investigate its impact on the fatigue behavior of the alloys. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Phase-Pure Hydroxyapatite/β-Tricalcium Phosphate Scaffolds from Ultra-Pure Precursors: Composition Governs Porosity, Strength, and SBF Kinetics(2025-11-01) ;Monviset, Panuwat; ;Khantachawana, AnakNaruphontjirakul, ParichartBiphasic calcium phosphate (BCP)scaffolds comprising hydroxyapatite (HA) and β-tricalcium phosphate (β-TCP) were produced from ultra-pure precursors and processed under an α-TCP–avoiding schedule (1100 °C, 2 h). Quantitative X-ray diffraction (Rietveld/Profex) detected no α-TCP above the ~1 wt% limit of detection and quantified post-sintering phase fractions (wt% HA/β-TCP): 99.26/0.74, 68.51/31.49, and 27.57/72.43. Across compositions, SEM/ImageJ yielded similar mean macropore sizes (≈71–80 µm), while open porosity increased with the HA fraction (27.5 ± 1.8%, 39.1 ± 2.0%, 57.1 ± 2.4%). Compressive strength decreased accordingly (1.07 ± 0.25, 0.24 ± 0.01, 0.05 ± 0.02 MPa), consistent with non-load-bearing use. In ISO-compliant simulated body fluid (28 d), medium pH remained stable (7.33–7.43); mass loss and early Ca<sup>2+</sup> depletion increased with β-TCP content, consistent with more extensive surface apatite formation in β-TCP-rich scaffolds. Collectively, these data are consistent with a composition-dependent sequence—β-TCP content → densification/porosity → strength → degradation/apatite kinetics—within the tested conditions and inform parameter-based tuning of BCP scaffolds for non-load-bearing indications (e.g., alveolar ridge preservation, craniofacial void filling).
