Damrongsak, Pattareeya
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Damrongsak, Pattareeya
Alternative Name
Damrongsak, P.
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Email
pattareeya.da@kmitl.ac.th
14 results
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Item type:Publication, Rhodamine 6G and Au–Pd core–shell nanorods: Fluorescence enhancement for detection of mercury(2018-01-01) ;Rammarat, Ekkachai ;Kraithong, Sasiwimon ;Wanichacheva, Nantanit ;Swanglap, PattanawitWe show that hybrid organic–inorganic particles are efficient for accurate sensing of mercury ions and following up trace amounts of the mercury pollutions spread in the environment. The process of synthesis of a working substance starts from preparation of rhodamine 6G derivative. Then the dye molecules are bound on the surface of Au–Pd core–shell nanorods. Mercury ions with different concentrations are finally attached onto this fluorescence sensor. Fluorescence emission of the sensor is detected with a luminescence spectrophotometer. The experimental results demonstrate that the fluorescence intensity of one of our sensors, a sensor B, is remarkably enhanced when the mercury-ion concentration increases from 0 to 15.5 µM. The limit of detection of the ions is as low as 20.6 nM. The working mechanism of our fluorescence sensor can be explained through the fluorescence-energy transfer and the plasmonic effect associated with spirolactam forms of rhodamine and conducting bimetallic nanoparticles. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Enhancement of fluorescence in inorganic dyes by metallic nanostructured surfaces(2016-01-01); We have studied the influence of shape and chemical content of metallic nanostructures (gold-palladium core-shell nanorods, gold nanobipyramids and single-crystalline porous palladium nanocrystals) on the luminescence of Rhodamine 6G and Coumarin153 dyes. The changes found in the emission intensity are attributed to different proportions of the dyes and the metallic nanostructures. The enhancement of the fluorescence observed by us for the cases of Rhodamine 6G with gold-palladium core-shell nanorods and Rhodamine 6G with gold nanobipyramids suggests their promising plasmonic properties. This may be regarded as a preliminary step towards development of the fluorescent probes possessing high photo-sensitivity. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Superhydrophobilization of SiO2 surface with two alkylsilanes for an application in oil/water separation(2018-04-01); ;Pasupong, Patchara; This study reported a novel approach to superhydrophobilize silica (SiO<inf>2</inf>) surface by silanizing with two alkylsilanes including non-polar short hydrocarbon chains of chlorotrimethylsilane (CTMS) followed by long hydrocarbon chains of octadecyltrichlorosilane (OTS). The silanization of CTMS prior to OTS affected the increase in the density of short and long alkyl chains throughout SiO<inf>2</inf> surface resulting in the surface with low surface energy and high degree of hierarchical micro-nanoscale roughness which were responsible for the superhydrophobicity. The oil/water separation filters prepared by coating cotton fabric with the CTMS- and OTS-modified SiO<inf>2</inf>/polystyrene (PS) composite using a weight ratio of the modified SiO<inf>2</inf>:PS at 2:1 possessed the highest water contact angles of 156° ± 1°. The superhydrophobic/superoleophilic filters showed excellent water repellent, oil/water separation efficiency, and reusability. The results obtained in this study suggest that salinizing the two different structure alkylsilanes, CTMS followed by OTS, can provide synergetic benefit in improving the superhydrophobicity by enhancing the density of alkyl chains on SiO<inf>2</inf> surface. This alternative strategy can be extensively applied for development of other superhydrophobic materials. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Microwave-activated reduced graphene oxide composite with hydrothermally treated corn husk activated carbon as an active electrode for high electrochemical performance in symmetrical carbon-based supercapacitor devices(2026-07-01) ;Srakaew, Khattiya ;Ratchayotee, Pornthip ;Janorat, Phattharawadee; This work applies microwaves for synthesizing reduced graphene oxide (rGO) and waste material corn husk activated carbon composites as active electrode materials for symmetric supercapacitors. The rGO is activated by microwave treatment and corn husk carbon by KOH in processed hydrothermal activation, followed by compositing at various weight ratios. Among all compositions, rGO:H_Corn_C (90:10) is reported with the best properties, with a specific surface area of 314.2 m2/g and a high specific capacitance of 1152 F/g at 0.1 A/g. The optimized composite also delivered increasing energy and power densities of up to 160 Wh/kg and 9.68 × 102 W/kg, respectively, within a 1 V operating window. In an experiment by assembling a symmetric coil cell supercapacitor, the device showed a specific capacitance of 142.23 F/g at 0.1 A/g, cycling stability with 98.8% capacitance retention after 1000 cycles of charge-discharge, and peak energy and power densities of 40.68 Wh/kg and 5.74 × 102 W/kg. Overall, the composite material with a high content of rGO and corn husk-derived activated carbon prepared by the hydrothermal method exhibits high-performance for the material in supercapacitor applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Optical imaging of artificial latent fingerprints using rhodamine 6G and au-core/Pd-shell nanorods(2019-01-01); Latent fingerprints represent valuable information-storage platforms, which play a key role in the forensic practice and health assessment. Recent works have explored novel image-enhancement methods in latent fingerprinting, which are associated with fluorescence dyes. In this study we improve the quality of fingerprint images, using a combination of fluorescence dyes and bimetallic nanoparticles. We find that Rhodamine 6G can serve as a kind of ‘glue’ adhering well onto Au–Pd core–shell nanorods. This system which employs molecules like α- amylase can be successfully used for recognition of artificial latent fingerprints. The appropriate mechanism can be coupling of localized surface plasmon resonance in the nanorods mentioned above and the emission of Rhodamine 6G. As a result, we observe notable enhancement of the images of artificial latent fingerprints. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Antitumor activities of carboplatin–doxorubicin–ZnO complexes in different human cancer cell lines (breast, cervix uteri, colon, liver and oral) under UV exposition(2021-01-01) ;Pairoj, Suttirak; ;Damrongsak, Badin ;Jinawath, NatiniKaewkhaw, RossukonThis study aimed to examine the pharmacological profiles of multiple chemo drug candidates in systematic circulation to enhance their specific interactions with five human cancer cell lines. ZnO nanoparticles were successfully bound with chemo drugs via physical adsorption. The drug loading capacity was confirmed by FTIR, whereas the loading efficiency was determined via UV–vis spectrometry. The mean hydrodynamic size increased to 69–82 nm after chemo-drug immobilization via non-covalent interaction with ZnO. Among the nine formulated chemo drugs, the carboplatin (CP)–doxorubicin (DOX)–ZnO complex under UV light irradiation exhibited high sensitivity towards human breast adenocarcinoma cells without affecting human keratinocyte immortal cells with an IC<inf>50</inf> of 0.137 µg/mL, whereas the loading capacity and efficiency of CP–DOX–ZnO were 77.81% and 99.05%, respectively. Fluorescence images confirmed that CP–DOX–ZnO using DOX served as a fluorescence enhancer specifically bound onto the cell membranes, which became almost saturated after 24 h incubation. Carboplatin–DOX–ZnO was possibly endocytosed by cancer cells and was selectively internalized into the target cells; thus, free chemo drug was released in the cytoplasm, which induced acute apoptosis. This resulted in complete inhabitation of growth signal of target cancer cells. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Kinetics of dye removal using Fe3O4 nanoparticles and pulsed white-LED illumination(2019-01-01); ; ;Hoomsuk, SirichaiRemoval of dyes with the aid of photocatalytic nanomaterials illuminated with continuous-light sources has been given substantial attention in the recent years. In the present work we study the efficiency of dye degradation using some alternative photocatalytic nanoparticles under condition of pulsed illumination. Our specific purpose is to investigate the removal of rhodamine 6G dye basing on suspended Fe<inf>3</inf>O<inf>4</inf> solution. The experiments are carried out in the batch mode when the effect of the exposition time (ranging from 30 to 150 min) on the dye removal is examined under both continuous and pulsed white-LED illuminations. Different pulsed-light frequencies and duty cycles are tested. We estimate the concentration of rhodamine 6G in the mixed solution following from its absorption spectrum measured with a UV-Vis spectrometer and determine in this manner the percentage of dye removal. Our main conclusion is that Fe<inf>3</inf>O<inf>4</inf> nanoparticles enable removing efficiently the rhodamine 6G dye under pulsed white-LED illumination. In particular, more than 90% of the dye is removed when the duty cycle is equal to 25% and the frequency to 30 kHz. The equilibrium state of this process is achieved in about 60 min. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effect of Adsorption Characteristics of Rhodamine 6G Dye Solution in Fe3O4 Magnetic Nanoparticles on Fluorescence Quantum Yield(2019-01-01) ;Phoemphoonthanyakit, Suwaphit; ; In this work, the use of Fe<inf>3</inf>O<inf>4</inf> magnetic nanoparticles in the adsorption of rhodamine 6G solution was evaluated via absorbance and fluorescence spectroscopy using the UV-Vis spectrometer. The adsorption mechanism of rhodamine 6G on Fe<inf>3</inf>O<inf>4</inf> was determined with respect to the adsorbent dosage (2.5-10 mg/L) and treatment time (0-150 min). The experimental data revealed that the fluorescence quantum yield of rhodamine 6G was inversely proportional to the percentage of dye removal. The highest efficiency of dye removal was obtained at 10 mg/L Fe<inf>3</inf>O<inf>4</inf>, and the adsorption capacity was about 150 mg/g, together with a reduced treatment time of 30 min, owing to active adsorption of Fe<inf>3</inf>O<inf>4</inf>. We believe that our study makes a significant contribution to the literature because Fe<inf>3</inf>O<inf>4</inf> magnetic nanoparticles were found to be able to quench rhodamine 6G dye molecules, which will aid in eliminating toxic and hazardous pollutants from dye wastewater, which are otherwise detrimental to the environment and human health. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Optical performance of fluorescent collectors integrated with microlens arrays(2017-09-01); Fluorescent collectors have been considered for being used as a light concentrator in photovoltaic applications. It is able to replace the expensive area of solar cells in order to minimize the energy cost. In this study, fluorescent collectors integrated with microlens arrays were developed in order to improve the collection efficiency. Fluorescent collectors were prepared by casting an epoxy resin solution containing Rhodamine 6G dye in the polydimethylsiloxane master mold. Polydimethylsiloxane-based microlens arrays with actual diameters of 804.06-1008.02 μm were fabricated using a replica molding technique. The microlens arrays were then integrated with the fluorescent collectors with various dye concentrations from 2.5 × 10<inf>-4</inf> to 4.5 × 10<inf>-4</inf> Molar. Experimental results were demonstrated that the implementation of polydimethylsiloxane microlens arrays on the top of fluorescent collectors was improved for both light absorption and fluorescent intensity. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Highly Hg2+-sensitive and selective fluorescent sensors in aqueous solution and sensors-encapsulated polymeric membrane(2016-01-01) ;Kraithong, Sasiwimon; ;Suwatpipat, Kullatat ;Sirirak, JitnapaSwanglap, PattanawitTwo Hg<sup>2+</sup> chemosensors, rhodamine B hydrazide (RBH) and rhodamine 6G hydrazide (R6GH), were synthesized by a single step. In the presence of Hg<sup>2+</sup>, both of the sensors RBH and R6GH exhibited highly sensitive OFF-ON fluorescence enhancement. Importantly, the sensors showed a selective binding to Hg<sup>2+</sup> over other common metal ions such as K<sup>+</sup>, Na<sup>+</sup>, Fe<sup>3+</sup>, Ca<sup>2+</sup>, Cu<sup>2+</sup>, Ag<sup>+</sup> and Pb<sup>2+</sup> in aqueous solutions. The OFF-ON fluorescence enhancement upon Hg<sup>2+</sup> binding could be ascribed to conformational change of the spirolactam moiety of the rhodamine fluorophore through a spirolactam ring opening process. Furthermore, encapsulation of the sensors by polymeric membranes (PMMA) provided high selectivity and high sensitivity, especially for the sensors-encapsulated polymeric membrane RBH that showed an extremely low detection limit (0.2 ppb), which was 245 times lower than the sensor RBH in aqueous solution. In addition to fluorescence enhancement, the presence of Hg<sup>2+</sup> also induced a noticeable color change from colorless to pink for the sensors dissolved in aqueous solution (10% v/v MeOH/water). The detection limits of sensor RBH and R6GH in both formats were in the range of 10<sup>-9</sup>-10<sup>-7</sup> M of Hg<sup>2+</sup> and were sufficient for on-site Hg<sup>2+</sup> detection in the environmental and biological systems such as ground water, drinking water and edible fish. In particular, the extremely high sensitivity of the novel sensors-encapsulated polymeric membrane RBH could pave the way for development of a real time Hg<sup>2+</sup> detection portable device.
