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    Machine learning of properties of lead-free perovskites with a neural network with additive kernel regression-based neuron activation functions
    (2024-07-01) ;
    Yoon, Heejoo
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    Hyojae, Lee
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    Kameda, Keisuke
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    Ihara, Manabu
    Machine learning (ML) of properties of perovskite materials, in particular of the bandgap of perovskites used in optoelectronic applications, has recently attracted increasing attention. Typically, off-the-shelf ML methods such as neural networks (NN), kernel methods or tree-based methods are used. We employ the recently proposed type of NN that uses additive Gaussian process regression to construct optimal neuron activation functions and avoids non-linear optimization to machine learn the band gap and heat of formation of lead-free inorganic halide double perovskites for solar cell applications. The method combines the high expressive power of an NN with the robustness of a linear regression. We show that better prediction quality can be obtained, in particular in the visible region relevant for most applications, compared to previous results using standard methods. Most important variables and the importance of coupling among features, in particular for bandgap prediction, can also be identified with the new method. Graphical abstract: (Figure presented.)
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    Remodelling hierarchical NiCo2O4@ZnS nanorods with multi-walled carbon nanotubes as a counter electrode for dye-sensitized solar cell applications
    (2026-12-01) ;
    Nachaithong, Theeranuch
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    Phumuen, Phatcharin
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    Wannabut, Wassana
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    Kunbuala, Neeraphat
    A hierarchical NiCo<inf>2</inf>O<inf>4</inf>@ZnS/MWCNT (NCO@Z-MWCNTs) nanocomposite was synthesized to serve as a platinum-free counter electrode for dye-sensitized solar cells (DSSCs). The nanocomposite comprised spinel NiCo<inf>2</inf>O<inf>4</inf> nanorods, ZnS associated with the surface of the nanorods, and an interconnected multi-walled carbon nanotube (MWCNT) network, and it was synthesized via a low-temperature solution-based hydrothermal method. XRD confirmed the presence of cubic NiCo<inf>2</inf>O<inf>4</inf> and zinc blende ZnS phases, while FESEM–EDS and XPS analyses verified the incorporation of ZnS and the formation of a conductive carbon framework interconnecting adjacent nanorods. ZnS, rather than acting as an isolated catalytic component, was considered to contribute additional sulfide-related surface sites and to modulate the interfacial electronic environment of the NiCo<inf>2</inf>O<inf>4</inf> nanorods, which likely facilitated redox reactions involving the I<sup>−</sup>/I<inf>3</inf><sup>−</sup> couple. Meanwhile, the MWCNT network established continuous electron transport pathways, effectively reducing interfacial resistance and enhancing charge-transfer efficiency. Thermogravimetric and electrochemical analyses revealed enhanced thermal stability, improved redox kinetics, and a significant reduction in charge-transfer resistance compared with pristine NiCo<inf>2</inf>O<inf>4</inf>.The optimized NCO@Z–MWCNT 9wt% counter electrode achieved a power conversion efficiency of 10.03% under AM 1.5 G illumination, exceeding that of the Pt reference device (9.6%). Overall, the improved performance was attributed to the combined contributions of ZnS surface modification and the conductive MWCNT network, which together enhanced charge transport and electrocatalytic activity. This work demonstrates a scalable strategy for developing cost-effective, durable, and high-performance counter electrodes for dye-sensitized solar cells.
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    Synergistic Ni–Cu/char bimetallic catalysts for enhanced hydrogen production from corn stover bio-oil via steam reforming
    (2026-01-01)
    Wongcharee, Surachai
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    Suriyachai, Nopparat
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    Kreetachat, Torpong
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    Jadsadajerm, Supachai
    Catalytic steam reforming of biomass-derived bio-oil offers a promising route for renewable hydrogen production, yet catalyst deactivation and coke formation limit its practical application, particularly for complex whole bio-oils. Herein, hydrogen production from corn stover-derived whole bio-oil was investigated via an integrated fast pyrolysis-steam reforming process using char-supported Ni–Cu bimetallic catalysts. The optimized Ni–Cu composition exhibited enhanced hydrogen yield (∼53%) and feedstock conversion (∼78%), with low carbon deposition compared to monometallic counterparts. Elevated reforming temperatures promoted hydrocarbon cracking and suppressed coke formation. Long-term stability tests demonstrated sustained catalytic performance under steam oxygen reforming conditions. Structural characterization confirmed uniform metal dispersion and preserved catalyst porosity after reaction. The improved performance is attributed to the synergistic interaction between Ni, facilitating C–C bond cleavage, and Cu, enhancing water–gas shift activity and mitigating carbon deposition. These findings highlight the potential of char-supported Ni–Cu catalysts as a robust and coke-resistant system for scalable hydrogen production from real biomass-derived bio-oil.
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    The Physical and Sound Absorption Property of Lightweight Rigid Polyurethane Composite Reinforced Bamboo Fiber for Roof Applications
    (2023-07-01)
    Roseli, Adyla Illyana
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    Hassan, Nik Normunira Mat
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    Leman, Abdul Mutalib
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    Latif, Najibah Abdul
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    Aminanda, Yulfian
    Rigid polyurethane (RPU) foams as roof insulation have become increasingly popular in Southeast Asian countries and have been extensively used for absorbing sound and reducing noise because of their good sound damping, viscoelasticity, and low density. In this study, the RPU foam composite reinforced bamboo fiber was investigated by physical characterization by SEM, TGA, and FTIR, and the sound absorption was measured by the Impedance Tube Test. The morphology result of the RPU foam composite indicates the size of the diameter pore influenced the sound absorption by adding bamboo fiber as a filler. The thermal degradation of the presence of lignin in the bamboo fiber at the temperature range of 400 °C to 500 °C and the total weight loss is 76 % at 429 °C temperature. FTIR spectrum shows that the peak at 2890 to 2935 cm-1 are indicated –CH stretching vibrations and characteristics for bamboo fiber can be used in polymer composites. The sound absorption of RPU 25 foam composite reinforced bamboo fiber was found 0.74 absorbance at a frequency of 1250 Hz. RPU foam reinforced bamboo fiber as a filler has the highest transmission loss RPU 35 is 21 dB at a frequency range of 1600 Hz. The findings indicate by increasing the content of bamboo fiber as filler, the diameter of the open pore of RPU 25 and RPU 35 foam composite had the potential for sound absorption to absorb at low frequency to achieve greater sound absorption for roof insulation.
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    Dataset of temperature and relative humidity measurements in domestic refrigerators in Bangkok Thailand
    (2026-08-01)
    Paviet-Salomon, Yvanne
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    Potisuwan, Cheeraphat
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    Derens-Bertheau, Evelyne
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    This dataset provides detailed measurements of internal air temperature, product temperature, and relative humidity in domestic refrigerators in households in Bangkok, Thailand. Data were collected from 123 households using Freshliance TagPlus-TH data loggers installed both inside and outside the refrigerators. For each refrigerator, air temperature and relative humidity were monitored at five internal locations: top shelf, middle shelf, vegetable drawer, door shelf, and freezer compartment. In addition, the temperature of a meat-like test product placed on the middle shelf was recorded. Ambient air conditions surrounding each refrigerator were also measured to characterize the external thermal environment. Prior to deployment, all sensors were prepared and activated by the research team, with time zero (T0) defined at this stage. Participants were only required to place the sensors according to the provided instructions while minimizing disturbances to their usual refrigerator usage habits. The sensors remained inside the refrigerators for seven consecutive days, recording measurements every 5 minutes before being removed. Data collected during the first and seventh days of monitoring were excluded from the analysis to account for the uncertainty regarding the exact times at which consumers placed and removed the sensors. This exclusion also helped eliminate transient effects caused by the introduction of heat loads during sensor installation and removal, which are not representative of normal refrigerator operating conditions. Consequently, only the five-day dataset corresponding to stabilized operating conditions is presented. The dataset is provided as tab-delimited.txt files. File names identify both the refrigerator number (1–123) and refrigerator configuration, including single-door, two-door top-freezer, and two-door bottom-freezer models. An accompanying R script enables the generation of temperature and humidity profiles for each refrigerator over the 5-day monitoring period. A README document is also included and provides detailed descriptions of column names, sensor locations, and metadata associated with each measurement campaign. Temperature sensors have a resolution of 0.1°C over a range of −30°C to +70°C, and an expanded uncertainty of ±0.5°C (k = 2). Relative humidity sensors have a resolution of 0.1 % and an expanded uncertainty of ±3 % (k = 2). These uncertainty values are based on the manufacturer’s specifications, additional calibration could not be performed within the scope of this study due to the lack of suitable calibration equipment. This high-resolution dataset provides valuable insights into the thermal and hygrometric conditions of domestic refrigeration systems under real household usage conditions. The data may support a wide range of applications, including the assessment and optimization of refrigeration performance through analysis of temperature heterogeneity and thermal behavior inside refrigerating compartments, the evaluation of food safety and risks associated with domestic storage temperatures, the identification of potential temperature abuse conditions in challenge-test studies, the development of consumer recommendations, the development and validation of simplified thermal models and CFD simulations for predicting airflow and heat transfer within domestic refrigerators, studies related to energy consumption and food preservation, and the optimization of domestic refrigerator design parameters using CFD and artificial neural network approaches. The dataset is expected to provide valuable insights for researchers, stakeholders, and policymakers working on refrigeration technologies, food safety, and cold-chain management.
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    Comparative analysis of anti-soiling coatings for PV modules in a tropical climate
    (2025-11-01)
    Sakarapunthip, Nattakarn
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    Sittipunsakda, Oranoot
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    Sangpongsanont, Yaowanee
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    Chuangchote, Surawut
    The accumulation of dust on photovoltaic (PV) modules significantly reduces their efficiency, making anti-soiling coatings (ASCs) an essential solution. However, comprehensive comparisons of different ASC technologies under real-world conditions remain limited. This study systematically evaluates four ASC types (surfactant, hydrophilic-photocatalyst, hydrophilic-antistatic, and hydrophobic coatings) to assess their adhesion strength, durability, anti-soiling performance, and impact on PV energy output in a tropical environment. Surface morphologies and elemental compositions of ASCs were analyzed using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS), while adhesion performance was examined through tape tests and contact angle measurements. The coatings were field-tested on PV modules in two distinct environments: a rooftop PV system near a mangrove area and a PV power plant near an agricultural zone, with data collected over both dry and rainy seasons. Results indicate that hydrophobic coatings exhibited the highest durability and anti-soiling efficiency, followed by hydrophilic-antistatic, hydrophilic-photocatalyst, and surfactant coatings. The hydrophobic coating also demonstrated the most significant improvement in PV energy output, making it the most effective long-term solution. Additionally, this study evaluates the environmental and economic feasibility of ASC application, highlighting the trade-offs between coating effectiveness and maintenance costs. These findings provide critical insights into selecting optimal ASC technologies for PV systems in high-soiling regions, bridging the gap between laboratory research and real-world performance.
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    Morphological, TGA, and FTIR on Rigid Polyurethane Composite Laminated with Untreated and Treated Bamboo Fiber Roof Insulation
    (2024-05-01)
    Roseli, Adyla Illyana
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    Hassan, Nik Normunira Mat
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    Leman, Abdul Mutalib
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    Latif, Najibah Abdul
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    Aminanda, Yulfian
    The performance of roof insulation such as polyurethane decreased due to problems such as insufficient absorption and poor thermal insulation performance, especially during rainstorms. The aims of this study are to investigate the physical property and its potential reinforced material such as rigid polyurethane doped with treated and untreated bamboo fiber composite (RPU-BF) at different ratios of 0, 25, 30, 35, and 40% of bamboo fibers as an insulation material for roof applications. The bamboo fibers were treated by using silane coupling agent treatment. The rigid polyurethane composite samples were prepared and then laminated bamboo fiber to overcome the sound problem in roofs. The physical characterization was investigated by Water Contact Angle (WCA), the morphological by Scanning Electron Microscopy (SEM), Thermo-gravimetric Analysis (TGA), and Fourier Transform Infrared Spectroscopy (FTIR) Analysis. The results showed that the treated bamboo fiber had a 192.5° water contact angle as a super hydrophobic property due to the presence of the chemical bonds Si-O-Si and Si-O-C in the silane coupling agent treatment. The morphology showed that 30% ratios of RPU-BF-T30 give the smallest pore diameter size. The peak of thermal degradation temperature of untreated and treated bamboo fiber was increased from 320°C to 350 °C with a weight loss of 80% to 50%. The treated bamboo fiber exhibited peaks at 3010–3040 cm<sup>-1</sup> were associated with stronger Si-O-Si bonding, indicating the formation of new chemical bonds between bamboo fiber and silane coupling agent due to the ester bond from the cellulose, lignin, and hemicellulose. Thus, there was a similar trend peak in the functional chemical group in the FTIR spectrum of the RPU-BF composite. This result shows that RPU-BF composite had the potential of the optimum ratio of bamboo fiber as an insulation material for local communities and beneficial to the bamboo industry.
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    Electrospinning of SnO2-TiO2nanofiber/nanorod composites for uses as electron transport layers in flexible perovskite solar cells
    (2024-05-17) ;
    Roongraung, Kamonchanok
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    Sanglee, Kanyanee
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    Lekkla, Wassana
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    Chuangchote, Surawut
    In perovskite solar cells (PSCs), the most commonly used electron transport layers (ETLs) are titanium dioxide (TiO2) and tin oxide (SnO2). The problem with SnO2 is that its conduction band does not match that of perovskites, while TiO2's photocatalytic nature can destroy perovskite materials. Additionally, these ETLs are typically applied in the form of nanoparticles. Electrospinning was used to produce composite nanofibers or nanorods of SnO2-TiO2 to improve the photovoltaic performance of flexible PSCs, which are required for flexible electronic devices. SnO2-TiO2 nanofibers or NRs as ETLs assist perovskites in harvesting light, separating excitons, extracting and collecting electrons, blocking holes, and preventing perovskites from decomposing and forming defects. PSCs containing SnO2-TiO2 nanoparticles have been produced. From the J-V characteristics of flexible-PSCs, the use of SnO2-TiO2 nanofibers improved the power conversion efficiency of the solar cells. A higher current density was obtained. This occurs because the 1D structure allows for more freely moving electrons. Comparing SnO2 nanoparticles and TiO2 nanofibers, an SnO2-TiO2 layer provides superior charge mobility and helps improve strength of the bonding at the perovskite/ITO interface. It is superior to SnO2 NPs and TiO2 nanofibers in reducing surface recombination.
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    Neural networks for neurocomputing circuits: A computational study of tolerance to noise and activation function non-uniformity when machine learning materials properties
    (2025-12-01)
    Thant, Ye min
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    Chueh, Chu Chen
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    Ihara, Manabu
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    Manzhos, Sergei
    Dedicated analog neurocomputing circuits are promising for high-throughput, low power consumption applications of machine learning (ML) and for applications where implementing a digital computer is unwieldy (remote locations; small, mobile, and autonomous devices, extreme conditions, etc.). Neural networks (NN) implemented in such circuits, however, must contend with circuit noise and the non-uniform shapes of the neuron activation function (NAF) due to the dispersion of performance characteristics of circuit elements (such as transistors or diodes implementing the neurons). We present a computational study of the impact of circuit noise and NAF inhomogeneity in regression problems as a function of NN architecture and training regimes. We focus on one application that requires high-throughput ML: materials informatics, using as representative problem ML of formation energies vs. lowest-energy isomer of peri-condensed hydrocarbons, formation energies and band gaps of double perovskites, and zero point vibrational energies of molecules from QM9 dataset. We show that in these applications, NNs generally possess low noise tolerance with the model accuracy rapidly degrading with noise level. Single-hidden layer NNs, and NNs with larger-than-optimal sizes are somewhat more noise-tolerant. Models that show less overfitting (not necessarily the lowest test set error) are more noise-tolerant. Importantly, we demonstrate that the effect of activation function inhomogeneity can be palliated by retraining the NN using practically realized shapes of NAFs.
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    Integrated Assessment of Rooftop Photovoltaic Systems and Carbon Footprint for Organization: A Case Study of an Educational Facility in Thailand
    (2025-05-01)
    Leeabai, Nattapon
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    Sakaraphantip, Natthakarn
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    Kunbuala, Neeraphat
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    Roongrueng, Kamonchanok
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    This study presents an integrated methodology to assess and reduce greenhouse gas (GHG) emissions in institutional buildings by combining organizational carbon footprint (CFO) analysis with rooftop photovoltaic (PV) system simulation. The HM Building at King Mongkut’s Institute of Technology Ladkrabang (KMITL), Thailand, was selected as a case study to evaluate carbon emissions and the feasibility of solar-based mitigation strategies. The CFO assessment, conducted in accordance with ISO 14064-1:2018 and the Thailand Greenhouse Gas Management Organization (TGO) guidelines, identified total emissions of 1841.04 tCO<inf>2</inf>e/year, with Scope 2 electricity-related emissions accounting for 442.00 tCO<inf>2</inf>e/year. Appliance-level audits revealed that classroom activities represent 36.7% of the building’s electricity demand. These findings were validated using utility data totaling 850,000 kWh/year. A rooftop PV system with a capacity of 207 kWp was simulated using PVsyst software (version 7.1), incorporating site-specific solar irradiance and technical loss parameters. Monocrystalline modules produced the highest energy output of 292,000 kWh/year, capable of offsetting 151.84 tCO<inf>2</inf>e/year, equivalent to 34.4% of Scope 2 emissions. Economic evaluation indicated a 7.4-year payback period, with a net present value (NPV) of THB 12.49 million and an internal rate of return (IRR) of 12.79%. The integration of verified CFO data with empirical load modeling and derated PV performance projections provides a robust, scalable framework for institutional carbon mitigation. This approach supports data-driven Net Zero campus planning aligned with Thailand’s Nationally Determined Contributions (NDCs) and carbon neutrality policies.