Kitiwan, Mettaya
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Kitiwan, Mettaya
Alternative Name
Kitiwan, M.
Main Affiliation
Email
mettaya.ki@kmitl.ac.th
13 results
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Item type:Publication, Optical Properties of CuCdS Thin Film Prepared by Vacuum Thermal Evaporation Technique(2023-01-01) ;Hankoy, Montree ;Treetornkeerati, Paramapat ;Fungfuang, Natasia; This study reports on the synthesis and characterizations of copper cadmium sulfide (CuCdS) thin films prepared using the vacuum thermal evaporation technique with copper sulfide and CdS as precursors in a 1:1 molar ratio. The structural properties of the thin films were analyzed using X-ray diffraction (XRD) which revealed that the main composition of the thin film was CdS with the preferred orientation of the (101) plane. The optical properties were examined using UV–Vis spectrophotometry. The photosensitivity of the films was determined using I–V measurements performed with a two-probe technique. The prepared CuCdS thin films have high optical transmittance of 92%. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Fabrication and characterization of lightweight aggregates with expanded perlite and NPK nutrient incorporation(2025-06-01) ;Rungrueng, Panadda ;Hankoy, Montree; ;Keawprak, NittayaThis study focuses on the development of porous lightweight aggregates incorporated with NPK fertilizer as a sustainable nutrient carrier for agricultural applications. The integration of expanded perlite (EP) as a pore-forming agent enabled the production of lightweight aggregates (EP-LWAs) at lower sintering temperatures (900 °C) while maintaining high porosity and water absorption properties, reducing energy consumption compared to conventional high-temperature ceramic processing. The optimized EP-LWAs exhibited a bulk density of 1.15 g/cm<sup>3</sup>, porosity of 46.09 %, and water absorption of 40.28 %, ensuring enhanced nutrient retention capacity. The fertilizer incorporation process was achieved using a simple vacuum infiltration technique, effectively loading the pellets with 1.2 % nitrogen (N), 2.6 % phosphorus (P), and 1.2 % potassium (K), surpassing typical soil nutrient levels and exhibiting comparable NPK content to organic fertilizers. These results highlight the potential of EP-LWAs as an energy-efficient and eco-friendly planting materials, offering a cost-effective for sustainable agriculture, green roof, and vertical gardening applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Modification of Al2O3-Based Membranes with Carbon Black for Enhanced Hydrogen Permeation(2025-11-01) ;Hankoy, Montree ;Rodchom, Mana ;Vichaphund, Supawan ;Atong, DuangduenZhang, JianfengThis work presents the development and characterization of alumina–carbon black (ACB) composite membranes for enhanced hydrogen separation performance. A series of membranes containing 0–3.0 wt.% carbon black was fabricated via high-temperature sintering and systematically investigated with respect to their structural, morphological, mechanical, and gas separation properties. The addition of carbon black significantly influenced membrane microstructure, promoting pore network formation, increasing specific surface area, and enhancing gas transport. Gas permeation tests using H<inf>2</inf> and N<inf>2</inf> revealed that all ACB membranes exhibited higher hydrogen permeance than the pure Al<inf>2</inf>O<inf>3</inf> membrane. Notably, the ACB3.0 specimen demonstrated the highest H<inf>2</inf> permeance of 508 × 10<sup>−6</sup> mol m<sup>−2</sup> s<sup>−1</sup> Pa<sup>−1</sup> at 303 K, which is nearly four times greater than the unmodified membrane. At an elevated temperature (773 K), H<inf>2</inf>/N<inf>2</inf> selectivity improved with increasing carbon black content, with ACB3.0 achieving a maximum selectivity of 3.82, exceeding the theoretical Knudsen value, suggesting a synergistic contribution of Knudsen diffusion and surface diffusion. These results demonstrate that carbon black is a cost-effective and versatile additive for modifying ceramic membranes, offering a promising route for advancing hydrogen purification technologies in industrial applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, A STUDY ON SiC SUSCEPTOR CONFIGURATION FOR MICROWAVE HYBRID HEATING(2023-01-01) ;Ngamkiatpaisan, Akawat ;Hankoy, Montree; ;Keawprak, NittayaMicrowave hybrid heating (MHH) is a novel method to enhance ceramic sintering at high temperatures. The heating mechanism by MHH involves two directions of heat transfer for materials: microwaves heat the sample from the inside out, while the susceptor provides conventional heating from the outside. This unique heating mechanism offers several advantages, including uniform heating, rapid sintering, and enhanced microstructure and properties of materials. This study investigates the configuration of silicon carbide (SiC) susceptors for microwave hybrid heating. The microwave oven (multi-mode, 2.45 GHz, 1.2 kW) was modified with a ceramic insulator housing to maintain the temperature in the chamber. The effects of different configurations of SiC susceptors and microwave powers on the heating rate and maximum temperature were investigated. SiC susceptor plates were placed in the microwave oven using 3 different configurations, and for each condition, the microwave power was varied at 40, 60, 80, and 100% (480, 720, 960, and 1,200 W). The temperature in the microwave chamber was recorded until it reached 900°C or after 30 min of heating. Using two plates of SiC susceptor at 100 % power resulted in the highest heating rate of 62°C/min to reach 925°C. The results of this study offer guidance for the selection of appropriate heating conditions for individual ceramic materials, which can lead to more effective sintering processes. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Influence of Expanded Perlite on Pore Structure and Physical Properties of Lightweight Aggregates Derived from Red Clay(2026-05-01) ;Moolpradab, Paniti ;Hankoy, Montree ;Zhang, Jianfeng ;Keawprak, NittayaThe utilization of locally sourced raw materials for lightweight aggregate (LWA) production has attracted increasing attention due to its potential for cost reduction and sustainable material development. This study investigates the effect of expanded perlite addition (10–40 wt%) on the physical, structural, and mechanical properties of LWAs derived from In Buri red clay, sintered at a relatively low temperature of 800 °C without a conventional high-temperature bloating process. X-ray diffraction (XRD) analysis revealed that quartz remained the dominant phase after sintering, with minor albite and residual illite, indicating limited phase transformation. Thermal analysis showed that major mass loss occurred below 600 °C, confirming that 800 °C is sufficient for removing volatile components. SEM observations demonstrated that increasing perlite content led to the development of a more porous and interconnected microstructure. As the expanded perlite content increased, the bulk density decreased from 1.31 to 0.80 g/cm<sup>3</sup>, while the apparent porosity and water absorption increased to 48.5% and 60.8%, respectively. Conversely, crushing strength decreased due to increased porosity. These results demonstrate that expanded perlite is an effective additive for tailoring the microstructure and performance of LWAs at low sintering temperature. The developed materials show strong potential for horticultural applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Comparative study of vacuum arc-remelting and spark plasma sintering processes on microstructure and corrosion behavior of Cp-Ti for biomedical implant applications(2025-11-01) ;Kunbuala, Neeraphat; ;Phamornnak, Chinnawich; Hankoy, MontreeTitanium (Ti) and its alloys are widely used for biomedical applications due to their excellent mechanical properties and biocompatibility. However, the selection of an appropriate manufacturing process is critical to ensuring the optimal performance of Ti-based implants. This study investigates the effects of two fabrication methods –vacuum arc remelting (VAR) and spark plasma sintering (SPS) – on the microstructure and corrosion behavior of commercially pure titanium (Cp-Ti). VAR-Ti ingots were fabricated using arc-melting with multiple remelting cycles, whereas SPS-Ti specimens were sintered from Ti powders under pressure and pulsed current in a high-vacuum environment. Both specimens were subsequently heat-treated at 800 °C and furnace cooled. Microstructural characterization revealed coarser grains and porosity in VAR-Ti, while SPS-Ti showed refined, uniform α-phase structures. Electrochemical tests, including OCP, polarization, EIS, and ICP-MS, indicated slightly enhanced corrosion resistance in SPS-Ti, attributed to its defect-free microstructure. XPS analysis confirmed TiO<inf>2</inf> surface formation on both samples. Additionally, both materials exhibited high ductility and excellent biocompatibility, with cell viability exceeding ISO 10993-5 thresholds. These findings highlight the advantage of SPS in producing defect-minimized Cp-Ti with improved corrosion behavior for biomedical applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Development of Sustainable Biomaterials Composites from Waste Materials (Spent Mushroom Compost, Garlic Shell, and Water Hyacinth) with Edible Mushroom Mycelium-Based(2026-01-01); ; Purpose: To evaluate performance and add value of bio-based degradable waste materials of spent mushroom compost cooperate with garlic shell, and water hyacinth with mushroom mycelium-based methods. Method: The Ganoderma lucidum, Lentinus polychrous, L. squarrosulus, and Pleurotus sajor-caju were used to study bio-based composites from various formula of waste materials (spent mushroom compost (Agrocybe cylindracea or P. ostreatus), garlic shell, and water hyacinth). Then we selected the best species and the formula of biomaterial composites to prepare pot prototypes. Finally, the biomaterial composite pots were measured physical and mechanical properties. Results: L. squarrosulus exhibited the fastest mycelial growth and highly effective to composed materials. Then, selected further pot prototypes with variation formulation and physical and mechanical properties were presented; density ranged from 0.18−0.22 g cm<sup>-3</sup> and water absorption reaching between 172−250% in 24 hr., the absorption increases more gradually, reaching 302%−368% after 168 hr. Variations between formulation, the composites AC-F1 and PO-F1 exhibited superior water absorption. Whereas composites AC-F2 and PO-F2 demonstrated the lowest water absorption. For the compressive strength significant differences between samples prepared with spent mushroom compost from A. cylindracea and P. ostreatus. The spent mushroom compost from P. ostreatus is higher compressive strength, ranging from 385.4−451.5 kPa. In contrast the spent mushroom compost derived from A. cylindracea ranged between 174.9−197.3 kPa. Conclusion: The mycelium-based biodegradable composite produced demonstrates excellent performance and suitability for various applications. As such, they contribute to efficient upcycling and support zero-waste practices. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Enhancing the hydrogen permeation of alumina composite porous membranes via graphene oxide addition(2023-01-12) ;Hankoy, Montree; ; ; Vichaphund, SupawanGraphene oxide (GO) membranes have attracted considerable interest for hydrogen (H<inf>2</inf>) purification applications. However, the addition of GO into matrix materials to enhance the efficiency of H<inf>2</inf> permeation remains a challenge. In this study, the fabrication of alumina/graphene oxide (AGO) composites containing varying contents of GO (0.5–3.0 wt.%) was investigated. The AGO composites were formed into pellets and sintered for 2 h at 1500 °C. Accordingly, the presence of GO in the membranes following sintering was confirmed by Raman spectroscopy. Additionally, the porosity of the AGO composites increased from 3.7% to 26.9% as the GO concentration increased from 0.5 wt.% to 3.0 wt.%. Furthermore, the average pore diameter of the AGO composites was in the range of 87–228 nm, and the pore size distribution was unimodal. The performance of the AGO membranes was investigated for the permeance of single gases H<inf>2</inf> and N<inf>2</inf> at 30–500 °C to evaluate their potential for H<inf>2</inf> separation applications. The AGO membranes with a GO addition of 2.5 and 3.0 wt.% exhibited a high hydrogen permeance of 232–410 × 10<sup>−6</sup> mol m<sup>−2</sup> s<sup>−1</sup> Pa<sup>−1</sup>, which was approximately 10 times greater than that of pristine Al<inf>2</inf>O<inf>3</inf> membrane. Additionally, the ideal H<inf>2</inf>/N<inf>2</inf> selectivity values ranged from 4.02 to 4.20. Furthermore, gas permeation through the AGO membrane was observed to follow the Knudsen diffusion mechanism. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, EFFECT OF h-BN AS AN ADDITIVE ON PHYSICAL AND MECHANICAL PROPERTIES OF Al2TiO5 COMPOSITE(2023-01-01) ;Treetornkeerati, Paramapat ;Hankoy, Montree; ;Rodchom, ManaVichaphund, SupawanAluminum titanate (Al<inf>2</inf>TiO<inf>5</inf>) is a promising material for high-temperature applications due to its low thermal expansion, high melting point, and excellent corrosion resistance. In this study, the effect of h-BN addition on the properties of Al<inf>2</inf>TiO<inf>5</inf> composites was investigated. The composites were prepared by sintering a mixture of Al<inf>2</inf>O<inf>3</inf> and TiO<inf>2</inf> at a 1:1 molar ratio, with varying amounts of h-BN (5-20 mol%) added to the mixture. The samples were sintered at 1,500ºC for 4 h in N<inf>2</inf> atmosphere, and the bulk density, porosity, phase transition, microstructure, flexural strength, and hardness of the composites were investigated. XRD analysis confirmed the presence of Al<inf>2</inf>TiO<inf>5</inf>, Al<inf>2</inf>O<inf>3</inf>, and Al<inf>18</inf>B<inf>4</inf>O<inf>33</inf> phases in the composites. The addition of h-BN in increasing amounts from 5 to 20 mol% resulted in a gradual improvement in the bulk density, flexural strength, and hardness of the Al<inf>2</inf>TiO<inf>5</inf> composites. The composite with the highest h-BN content (20 mol%) exhibited a bulk density of 3.12 g/cm<sup>3</sup>, as well as the highest flexural strength and hardness values of 123.6±8.9 MPa and 11.2±4.1 GPa, respectively. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Characterization of Fluoride-added Hydroxyapatite Derived from Eggshells for Dental Application(2023-01-01) ;Uthayaphamornwat, Vilasinee ;Khantachawana, Anak; ; Hydroxyapatite (HA) is one of the potential biomaterials used for treating dental defects. It can be incorporated with fluoride to enhance its anti-caries properties, though other properties could be dependent on processing technique. Hence, this study aims to characterize the influence of sintering on the properties of fluoride-added HA derived from eggshells. FTIR and XRD techniques are used to characterize the chemical and crystal structures of the samples, whilst dissolution test is carried out to characterize material degradation in the acidic environment. The results show that sintering increased the crystallinity in both HA and fluoride-add HA (F-HA) samples, which corresponds with the enhanced stability during the dissolution test. Moreover, it is also found that the addition of fluoride could further stabilize the material structure, though the impurities found in all the samples still need to be minimized. These findings suggest that sintering and fluoride addition could potentially enhance anti-caries properties of eggshell-derived HA, which could be beneficial for dental application in future subject to further process optimization and analysis.
