Muanghlua, Rangson
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Muanghlua, Rangson
Alternative Name
Muanghlua, R.
Muanghlua, Rangsan
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rangson.mu@kmitl.ac.th
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Item type:Publication, Rapid synthesis of potassium sodium niobate (K 1/2Na 1/ 2NbO3) lead-free piezoelectric powder using the combustion method(2013-12-01) ;Chaiyo, Nopsiri; ; ; Potassium sodium niobate (K1/<inf>2</inf>Na1/<inf>2</inf>NbO<inf>3</inf>) powder was synthesized successfully by the combustion synthesis. The raw materials of KNO<inf>3</inf>, NaNO<inf>3</inf> and Nb<inf>2</inf>O<inf>5</inf> were used with glycine as fuel. The thermal behaviour of the precursor was determined using thermo gravimetric analysis (TGA) and derivative thermo gravimetric (DTG) analysis. The conditions for preparing perovskite phase formation, influence of the fuel-to-oxidizer molar ratio, and crystal structure were characterized by the X-ray diffraction technique (XRD) and Fourier transform infrared (FTIR) spectroscopy. The morphology and particle size were investigated through a scanning electron microscope (SEM). © 2013 Copyright Taylor and Francis Group, LLC. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Non-isothermal kinetics of the thermal decomposition of sodium oxalate Na2C2O4(2012-03-01) ;Chaiyo, Nopsiri; ;Niemcharoen, Surasak; The thermal transformation of Na<inf>2</inf>C<inf>2</inf>O<inf>4</inf> was studied in N<inf>2</inf> atmosphere using thermo gravimetric (TG) analysis and differential thermal analysis (DTA). Na<inf>2</inf>C<inf>2</inf>O<inf>4</inf> and its decomposed product were characterized using a scanning electron microscope (SEM) and the X-ray diffraction technique (XRD). The non-isothermal kinetic of the decomposition was studied by the mean of Ozawa and Kissinger-Akahira-Sunose (KAS) methods. The activation energies (Eα) of Na<inf>2</inf>C<inf>2</inf>O<inf>4</inf> decomposition were found to be consistent. Decreasing Eα at increased decomposition temperature indicated the multi-step nature of the process. The possible conversion function estimated through the Liqing-Donghua method was 'cylindrical symmetry (R <inf>2</inf> or F<inf>1/2</inf>)' of the phase boundary mechanism. Thermodynamic functions (DH*, DG* and DS*), calculated by the Activated complex theory and kinetic parameters, indicated that the decomposition step is a high energy pathway and revealed a very hard mechanism. © Akadémiai Kiadó, Budapest, Hungary 2011. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effects of BiMO3 on dielectric, ferroelectric, and piezoelectric properties of perovskite lead-free piezoelectric BaTiO3–(Bi0.5Na0.5)TiO3 ceramics(2017-07-01) ;Chaiyo, Nopsiri; ; New lead-free piezoelectric ceramics of 0.9BaTiO<inf>3</inf>–(0.1−x)(Bi<inf>0.5</inf>Na<inf>0.5</inf>)TiO<inf>3</inf>–xBiMO<inf>3</inf>, M=Al and Ga, where x=0.00-0.10, were fabricated by the solid-state reaction technique. The effect of BiMO<inf>3</inf> contents on the perovskite structure, phase transition, and dielectric, ferroelectric, and piezoelectric properties was investigated. X-ray diffraction patterns showed that the ceramics exhibit a monophasic perovskite phase up to x=0.06, suggesting stabilized perovskite structures with B-site aliovalent substitutions. Compositional-dependent phase transitions were observed from tetragonal to pseudo-cubic phase with increasing BiMO<inf>3</inf> amounts. Al<sup>3+</sup> ions were found to stabilize the transition temperature of the ceramics, while significantly decreasing transition temperature, and a change in the dielectric peak were found with an increasing amount of Ga<sup>3+</sup>. Regarding Al<sup>3+</sup> substitution, the remanent polarization (P<inf>r</inf>) values were found to decrease slightly with the Al<sup>3+</sup> amount. With regard to Ga<sup>3+</sup> substitution, P<inf>r</inf> values decreased with the Ga<sup>3+</sup> amount up to 0.06 and then increased slightly. The ceramics became softer with a higher degree of substitution according to the lower coercive field (E<inf>c</inf>), when compared with 0.9BaTiO<inf>3</inf>–0.1(Bi<inf>0.5</inf>Na<inf>0.5</inf>)TiO<inf>3</inf> ceramics. Ceramics with a lower degree of substitution and tetragonal phase showed butterfly strain loops that correlated with normal ferroelectric behavior. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Combustion synthesis of lead-free piezoelectric alkali metal niobate family(2013-01-01) ;Chaiyo, Nopsiri; ; ; Nano-crystalline alkali metal niobate (ANbO<inf>3</inf>; A = K and Na) powders were synthesized by the combustion of nitrate compounds and Nb <inf>2</inf>O<inf>5</inf> using glycine as the fuel. The chemical reaction, nucleation mechanisms and influence of the fuel-to-oxidizer ratio to phase formation were studied. The precursor and product powders were characterized, using the thermo gravimetric analysis (TGA), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) technique, and scanning electron microscopy (SEM). Different fuel-to-oxidizer ratios were found to be a key factor of the process. As-prepared and calcined powders provided the perovskite structure with a nano-scale of mean crystalline size. © 2013 Copyright Taylor and Francis Group, LLC. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Preparation and properties of lead free bismuth sodium titanate-bismuth zinc titanate ceramics(2009-12-01); ;Niemcharoen, Surasak; ;Tungsitvisetkul, NattapongChinwaro, PimjanLead-free piezoelectric ceramics based on (1-x)Bi1/2Na1/2TiO3 - x Bi(Zn1/2 Ti1/2)O3 (x = 0.0, 0.02, 0.04, 0.06, 0.08, 0.10, 0.20, 0.30, 0.40, and 0.5) were obtained via solid-state processing techniques. The influence of BZT addition on BNT characteristics, sintering, microstructure and properties was investigated. A single perovskite phase with rhombohedral symmetry was obtained for Bi(Zn1/2Ti1/2)O3 substitutions of up to 10 mole%. A small amount of BZT was effective for improving both sintering behavior and dielectric properties of BNT ceramics. Optimized dielectric properties were obtained for samples with a maximum density of ρ = 98.3% for the composition, x = 0.1. Copyright © Taylor & Francis Group, LLC. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Synthesis and morphology evolution of lead-free piezoelectric K 1/2Na1/2NbO3 powder at low temperature(2009-12-01) ;Chaiyo, Nopsiri ;Ruangphanit, Anucha; ;Niemcharoen, SurasakSangseub, AtcharaA synthetic route for modified solid state reaction has been developed for the synthesis of the perovskite phase of potassium sodium niobate, K1/2Na1/2NbO3 (KNN). Potassium oxalate monohydrate (K2C2O4.H2O) and sodium oxalate (Na2C2O4) were employed as a source of potassium and sodium, respectively. The formation of the K1/2Na1/2NbO3 phase was investigated as a function of calcination conditions by TG-DTA and XRD techniques. Morphology and particle size were determined via an SEM technique. It was found that the minor phases of Na2CO3 and K2CO3 tend to form together with K1/2Na1/2NbO3, depending on calcination conditions. The perovskite phase was successfully synthesized at a low temperature of 400°C. As calcination temperatures increased from 600° to 850°C, the KNN solid solution became more homogeneous, XRD peaks became narrower, and a pattern similar to that expected for orthorhombic K1/2Na1/2NbO3 was achieved after 600°C, as indicated by the separate peaks of 0 2 2 and 2 0 0. Copyright © Taylor & Francis Group, LLC. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Synthesis of potassium niobate (KNbO3) nano-powder by a modified solid-state reaction(2011-03-01) ;Chaiyo, Nopsiri ;Ruangphanit, Anucha; ;Niemcharoen, SurasakCrystalline lead-free piezoelectric potassium niobate (KNbO<inf>3</inf>) powders have been synthesized through a modified solid-state reaction method. The thermal behavior of the K<inf>2</inf>C<inf>2</inf>O<inf>4</inf>-H <inf>2</inf>O and Nb<inf>2</inf>O<inf>5</inf> raw material mixture was investigated by thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The X-ray diffraction technique (XRD) was used to investigate the phase formation and purity. The morphology of the powder obtained was characterized using a scanning electron microscope (SEM). The XRD pattern showed that the monophasic perovskite phase of KNbO<inf>3</inf> could be synthesized successfully at a temperature as low as 550 °C for 240 min, with an average crystallite size of 36 ± 8 nm. The SEM images suggested that the average particle size of the powder obtained was 278 ± 75 nm. © Springer Science+Business Media, LLC 2010. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Solution combustion synthesis and characterization of lead-free piezoelectric sodium niobate (NaNbO3) powders(2011-02-03) ;Chaiyo, Nopsiri; ;Niemcharoen, Surasak; Nano-crystalline sodium niobate (NaNbO<inf>3</inf>) powder was synthesized by the solution combustion synthesis of sodium nitrate (NaNO<inf>3</inf>) and Nb<inf>2</inf>O<inf>5</inf> using glycine as the fuel. The chemical reaction, nucleation mechanisms and influence of the fuel-to-oxidizer ratio to phase formation were studied. The precursor and product powders were characterized, using thermo gravimetric analysis (TGA), differential thermal analysis (DTA), the X-ray diffraction technique (XRD), scanning electron microscope (SEM) and Fourier transform infrared (FTIR) spectroscopy. As-prepared powder possesses an orthorhombic crystal structure with an X-ray diffraction pattern that could be matched with the perovskite, NaNbO<inf>3</inf> JCPDS no. 82-0606. Perovskite NaNbO<inf>3</inf> phase, with a mean crystalline size (calculated by X-ray line broadening) ranging from 44.51 ± 11.99 nm (ratio of 0.7) to 26.11 ± 13.69 nm (ratio of 2.0) was obtained. The SEM image shows polyhedral-shaped powder with a mean particle size of 137 ± 52 nm and 226 ± 46 nm for as-prepared and calcined powder, respectively. © 2010 Elsevier B.V. All rights reserved.
