Khemasiri, Narathon
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Khemasiri, Narathon
Alternative Name
Khemasiri, N.
Email
narathon.kh@kmitl.ac.th
13 results
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Item type:Publication, ZnO Nanorods Grown on Heterogenous Ag Seed Layers for Single-Cell Fluorescence Bioassays(2021-07-23) ;Muensri, Phitchaya ;Treetong, Alongkot ;Namdee, Katawut ;Kasamechonchung, PanitaWutikhun, TuksadonHere we demonstrate the controllability of the morphology of hydrothermal ZnO nanorods (ZnO-NRs) grown on heterogenous Ag seed layers. By varying the crystal orientation of silver thin films (Ag), a high density of ZnO-NRs could be obtained. We find that the density of ZnO-NRs strongly relates to the peak intensity ratio between (111) and (200) planes of Ag thin films due to a heteroepitaxy between (0002) ZnO and (111) Ag rather than that of grain boundary nucleation and/or surface nucleation. In addition, the optimized heterostructure of ZnO nanorod/Ag arrays is investigated via a critical concentration for nucleation and used as a fluorescence enhancement substrate (FES). The experimental results have shown that the FES presents an ability to detect a biological sample (PC-3 cell) with a high sensitivity and low detection limit of 1 cell/μL. Our results highlight that understanding an important key to control and design the morphology of heterogeneous hydrothermal ZnO-NR growth is essential to open up the opportunities for fundamental studies and applications in high-performance integrated nanodevices. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Annealed zno/al2o3 core-shell nanowire as a platform to capture rna in blood plasma(2021-07-01) ;Takahashi, Hiromi ;Yasui, Takao ;Klamchuen, Annop; Wuthikhun, TuksadonRNA analytical platforms gained extensive attention recently for RNA-based molecular analysis. However, the major challenge for analyzing RNAs is their low concentration in blood plasma samples, hindering the use of RNAs for diagnostics. Platforms that can enrich RNAs are essential to enhance molecular detection. Here, we developed the annealed ZnO/Al<inf>2</inf>O<inf>3</inf> core-shell nanowire device as a platform to capture RNAs. We showed that the annealed ZnO/Al<inf>2</inf>O<inf>3</inf> core-shell nanowire could capture RNAs with high efficiency compared to that of other circulating nucleic acids, including genomic DNA (gDNA) and cell-free DNA (cfDNA). Moreover, the nanowire was considered to be biocompatible with blood plasma samples due to the crystalline structure of the Al<inf>2</inf>O<inf>3</inf> shell which serves as a protective layer to prevent nanowire degradation. Our developed device has the potential to be a platform for RNA-based extraction and detection. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Selective formations of antimony-dopant for highly sensitive nitrogen dioxide responsive behavior of tin oxide-based chemiresistive sensor(2025-02-15) ;Rattanawarinchai, Prapakorn; ; ; Here, selective formation of antimony (Sb) dopant species responsible for highly sensitive gas sensors based on tin oxide (SnO<inf>2</inf>) film grown via pulsed laser deposition is presented. By elevating a forming energy through controlling substrate temperature, not only crystallinity of Sb-SnO<inf>2</inf> (ATO) is notably enhanced but the Sb<sup>5 +</sup> also predominantly replace at Sn<sup>4+</sup> site rather than Sb<sup>3+</sup> counterpart. Such Sb-species selection plays a crucial role on the density of oxygen vacancy and free electron enabling to rationally design conductive behaviour of ATO film from insulative to degenerated semiconductor. As a practical example, detection of nitrogen dioxide (NO<inf>2</inf>) gas is selected as an application model. We found a narrow window for high NO<inf>2</inf> sensing performance of ATO film which strongly corresponds with the amount of carrier density. At certain window, ATO film exhibits high NO<inf>2</inf> response of 24.65 (10 ppm) and low limit of detection of 0.5 ppm, which is 5-fold higher and 10-fold lower than that of undoped-SnO<inf>2</inf>, respectively. Our finding demonstrates a facile approach to design over the chemical state, defect, and conductivity of the active sensing layer, allowing us to achieve an excellent sensing performance of functional materials conjugated to a nano-electronic platform. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Influence of Antimony Species on Electrical Properties of Sb-Doped Zinc Oxide Thin Films Prepared by Pulsed Laser Deposition(2023-06-01) ;Jessadaluk, Sukittaya; ; ; This study systematically investigates the influence of antimony (Sb) species on the electrical properties of Sb-doped zinc oxide (SZO) thin films prepared by pulsed laser deposition in an oxygen-rich environment. The Sb species-related defects were controlled through a qualitative change in energy per atom by increasing the Sb content in the Sb<inf>2</inf>O<inf>3</inf>:ZnO-ablating target. By increasing the content of Sb<inf>2</inf>O<inf>3</inf> (wt.%) in the target, Sb<sup>3+</sup> became the dominant Sb ablation species in the plasma plume. Consequently, n-type conductivity was converted to p-type conductivity in the SZO thin films prepared using the ablating target containing 2 wt.% Sb<inf>2</inf>O<inf>3</inf>. The substituted Sb species in the Zn site (Sb<inf>Zn</inf><sup>3+</sup> and Sb<inf>Zn</inf><sup>+</sup>) were responsible for forming n-type conductivity at low-level Sb doping. On the other hand, the Sb–Zn complex defects (Sb<inf>Zn</inf>–2V<inf>Zn</inf>) contributed to the formation of p-type conductivity at high-level doping. The increase in Sb<inf>2</inf>O<inf>3</inf> content in the ablating target, leading to a qualitative change in energy per Sb ion, offers a new pathway to achieve high-performing optoelectronics using ZnO-based p–n junctions. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Electroreflectance study of antimony doped ZnO thin films grown by pulsed laser deposition(2021-10-01) ;Jessadaluk, Sukittaya; ;Rattanawarinchai, Prapakorn; In this research, antimony doped ZnO (SZO) thin films with various doping content have been grown on a c-Al<inf>2</inf>O<inf>3</inf> substrate by pulsed laser deposition. The effect of the applied electric field on the bandgap of SZO thin films was studied by electroreflectance (ER) spectroscopy using a capacitor-type geometry. Hall effect measurements indicate that the p-type conductivity of SZO is realized for the Sb<inf>2</inf>O<inf>3</inf> weight percentage at 2%. The blue shift of the energy bandgap was observed in thin films after increasing the doping concentration. The Burstein-Moss effect is the crucial mechanism for the blue shift of the SZO bandgap. Furthermore, we found the red shift of bandgap in all samples, which was measured under various electric fields by ER spectroscopy. The changes of the optical transition in the band structure should be the origin of the red shift behaviors of the SZO bandgap under the presence of the electric field. Based on our results, we can design and optimize the bandgap of SZO for optoelectronic devices. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Laser-induced graphene electrochemical immunosensors for rapid and sensitive serological detection: A case study on dengue detection platform(2025-06-01) ;Inlumphan, Supawee; ; ;Rattanawarinchai, PrapakornLeepheng, PiyawanHere, we present a diagnostic on a chip platform based on laser-induced graphene (LIG) electrochemical immunosensors for serological detection. The electrochemical immunosensors are fabricated through CO<inf>2</inf> laser induction on polyimide (PI) sheets. Optimal electrochemical activity of LIG electrodes is obtained under optimized conditions of laser fluence. To verify the application, the serological detection platform was demonstrated. After functionalization with dengue virus (DENV) antigen, the LIG electrochemical immunosensors are able to sense the presence of mouse anti-flavivirus monoclonal (4G2) antibody in a wide linear working range of 25–20,000 ng/ml with the limit of detection (LOD) of 17.41 ng/ml. A specific recognition with 4G2 antibodies against with media protein and isotype is confirmed. Furthermore, the reliability of LIG electrochemical immunosensors compared to conventional enzyme-linked immunosorbent assay (ELISA) is verified through the NS1 antibodies identification in human blood serum clinical samples at room temperature. Our results highlight that the LIG-based electrode is a promising platform for electrochemical immunosensors, aimed at developing reliable and practical diagnostic tools for serological detection. These tools enable early diagnosis of infectious diseases, as well as non-invasive and rapid screening. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Tailoring ZnO Nanostructures through Precursor Concentration and Hydrothermal Duration: A Pathway to Efficient Solar Water Splitting(2026-11-10) ;Borklom, Phanlapa; ;Jessadaluk, Sukittaya ;Rattanawarinchai, PrapakornThis work investigated the formation of ZnO nanostructures on ITO substrates prepared by self-seeding hydrothermal synthesis for photoelectrochemical ( PEC) water splitting applications. The hydrothermal parameters, precursor concentration and hydrothermal time, were varied to explore their influences on ZnO crystallinity, morphology, and PEC performance. The combinations of X-ray diffraction and field emission scanning electron microscopy revealed highly oriented ZnO nanostructures with diverse morphologies, including small granules, nanorods, dense films, and hexagonal platelets. Topographic profiling of the morphological parameters revealed complex relationships between synthesis conditions and nanostructure characteristics, highlighting the importance of considering aggregation phenomena in substrate-based growth. This aggregation led to deviations from conventional crystal growth theory predictions, particularly for grain density and diameter evolution. PEC performance evaluation identified ZnO nanorods as the optimal morphology, exhibiting a photocurrent density of 0.182 mA/cm² at 0 V vs. Ag/AgCl. Further enhancement was achieved by decorating ZnO nanorods with CdS nanoparticles, resulting in a six-fold increase in photocurrent density (1.2 mA/cm²). This improvement is attributed to expanded light absorption and improved charge separation at the CdS/ ZnO interface. Our findings demonstrate the potential of rationally designed ZnO-based nanostructures in the advancement of solar-driven water splitting technologies and provide valuable insights for optimizing PEC systems through precise control of hydrothermal synthesis parameters, consideration of substrate-induced aggregation, and strategies for photoelectrochemical (PEC) water splitting applications. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Growth window and metal-insulator transition behavior of VO2 thin films deposited by pulsed laser deposition for thermal switch applications(2026-05-01) ;Jessadaluk, Sukittaya; ; ; Vanadium dioxide (VO<inf>2</inf>) is a strongly correlated transition metal oxide that exhibits a sharp and reversible metal-insulator transition (MIT) near room temperature, making it a promising material for thermal switching and adaptive electronic applications. In this study, VO<inf>2</inf> thin films were deposited on single-crystalline Si, thermally grown SiO<inf>2</inf>, and fused quartz substrates by pulsed laser deposition, and the influence of substrate temperature and oxygen partial pressure on phase formation, structural properties, and MIT behavior was systematically investigated. By optimizing deposition conditions within a narrow oxygen pressure window, phase-pure monoclinic VO<inf>2</inf>(M) thin films with high crystalline quality were achieved while suppressing the formation of over-oxidized vanadium oxide phases. Structural and chemical analyses using X-ray diffraction, Raman spectroscopy, and X-ray photoelectron spectroscopy confirmed the stabilization of the V4+ oxidation state and uniform film stoichiometry. Temperature-dependent electrical measurements revealed a pronounced and reproducible MIT characterized by an abrupt change in resistance and a clear thermal hysteresis. In-situ temperature-dependent X-ray diffraction further demonstrated a direct correlation between the monoclinic-rutile structural transformation and the electronic transition. Importantly, the MIT behavior was consistently observed across all investigated substrates, indicating robust film growth and substrate tolerance. These results provide insight into the structure-property relationships governing VO<inf>2</inf> thin films and highlight their potential for integration into thermal switch and thermally adaptive device architectures. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Systematic investigations on morphological properties of aluminum-doped zinc oxide transparent electrode prepared from pulsed laser deposition and its electrochromic application(2023-03-01); ;Klamchuen, Annop ;Jessadaluk, Sukittaya ;Rattanawarinchai, PrapakornBorklom, PunlapaTransparent electrode (TE) is considered as one of the fundamental components in the optoelectronics. The surface of TE layer plays a crucial role in the charge-transport characteristics. Herein, a systematic investigation on the morphological properties of the laser-ablated aluminum-doped zinc oxide (AZO) films as a TE material prepared from various laser fluences is demonstrated. It is revealed that the electrical properties of AZO films are strongly associated with their surface properties rather than that of the bulk film. As the laser fluence increased, the concentration of Al-dopant in AZO films is decreased which directly impacts on the electrical properties. Such vanishment is originated from the bombardment of the incident particles/ions with excessive kinetic energy on film's surface during the deposition. Moreover, the optimized AZO film with low resistivity (1.13 × 10<sup>−3</sup> Ω cm) and high optical transmittance (over 90%) achieved from controlling the laser fluence at 0.7 J/cm<sup>2</sup> is employed as TE layer in the electrochromic device. Our results highlight that the surface properties of TE layer are very critical for electronic performance. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Low resistance bisphenol-A based polybenzoxazine derived laser-induced graphene (LIG) and its microsupercapacitor application(2024-11-01) ;Luengrojanakul, Panuwat ;Klamchuen, Annop; ;Chotsuwan, ChuleekornCharoensuk, KrittapasHerein, we demonstrate the use of conventional BA-a based polybenzoxazine as a laser-induced graphene (LIG) forming precursor. The effects of laser power and the engraving speed on formation and properties of LIG are explored. By optimizing the laser fluency related to laser power along with engraving speed, poly(BA-a) derived LIG with high graphitization degree and low sheet resistance (R<inf>s</inf>) of ∼ 2–10 Ω/sq can be acquired. The morphologies and surface area of LIGs in such low R<inf>s</inf> region are then validated through SEM and BET, respectively. The resulting poly(BA-a) derived LIG exhibits a high amount of macropores in the structure with marginal differences in the specific surface area being 27–88 m<sup>2</sup>/g. In addition, electrochemical performances of the two-electrode based microsupercapacitor (LIG-MSC) of the selected samples in low R<inf>s</inf> region with different specific surface area are evaluated. The LIG-MSC shows a specific capacitance of 1.39 mF/cm<sup>2</sup> (0.04 mA/cm<sup>2</sup>), and good cycling stability of 10,000 cycles with capacitance retention of 92% (0.2 mA/cm<sup>2</sup>). Our results highlight that poly(BA-a) derived LIG is promising for high performance LIG applications.
