Nukeaw, Jiti
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Nukeaw, Jiti
Alternative Name
Nukeaw, J.
Nukeaw, Jitti
Nukeaw, Jiji
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jiti.nu@kmitl.ac.th
79 results
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Item type:Publication, Optical band engineering of metal-oxynitride based on tantalum oxide thin film fabricated via reactive gas-timing RF magnetron sputtering(2016-11-25); ;Jessadaluk, S. ;Chananonnawathorn, C. ;Vuttivong, S.Lertvanithphol, T.In this paper, we demonstrate a novel technique, as called reactive gas-timing (RGT) RF magnetron sputtering, to control and design an optical band engineering of TaON thin films without an external heating substrate temperature and post annealing treatment process. The influence of the oxygen intervals ranged from 5 to 60 s on deposition rate, chemical composition and optical properties of TaON thin films were investigated. The chemical composition was characterized by auger electron spectroscopy (AES). The optical properties were determined by UV–Vis spectrophotometer and spectroscopic ellipsometry. The nitrogen atomic concentration of the TaON thin films deposited by RGT decreased when the oxygen gas-timing intervals increased. In addition, the RGT sputtered TaON films could be demonstrated band gaps engineering from 1.90 to 2.15 eV. - Some of the metrics are blocked by yourconsent settings
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Item type:Publication, UV-enhanced photodetector with nanocrystalline-TiO 2 thin film via CMOS compatible process(2011-12-01) ;Bunjongpru, W. ;Panprom, P. ;Porntheeraphat, S. ;Meananeatra, R.Jeamsaksiri, W.This research presents nanocrystal titaniumdioxide (nanocrystal-TiO <inf>2</inf>) film deposition technique with CMOS compatible process [1] to extend the optical response bandwidth of silicon based photodetecting devices toward ultraviolet range [2]. The thin films were initially deposited as Titanium Nitride (TiN) using DC magnetron reactive sputtering system. It was then annealed under nitrogen atmosphere at 800°C. After analyzing crystal structures and surface morphology with X-ray diffraction and FE-SEM systems, it was found that the deposited thin films showed the crystal phase of TiO <inf>2</inf> oriented along (200) plane of Rutile crystal structure with 50 nm grain size and increasing with film thickness. Using electroreflectance (ER) spectroscopy measurement [3], the bandgap of nanocrystal-TiO <inf>2</inf> was revealed to be 3.16 eV. PN-heterojunction photodiodes were fabricated with Nanocrystal-TiO <inf>2</inf>/SiO <inf>2</inf>/p-Si structures. Interdigitated aluminum structures were used as electrodes. By varying the thickness of nanocrystal-TiO <inf>2</inf> film, i.e. 30, 60, and 90 nm, the devices could response further into the UV range. The absorption edge wavelength investigated by photoresponse measurement was at 275 nm and shifting to the shorter wavelength as a function of the nanocrystal-TiO <inf>2</inf> grain size due to quantum confinement phenomenon [4]. The nanocrystal-TiO <inf>2</inf>/SiO <inf>2</inf>/p-Si photodetector had dark current = 5.31nA (2V), photocurrent = 0.9 uA, rise time = 58 us, fall time = 47 us at 30 nm thickness of TiO <inf>2</inf>. © 2011 IEEE. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Improved selectivity, response time and recovery time by [0 1 0] highly preferred-orientation silicalite-1 layer coated on SnO2 thin film sensor for selective ethylene gas detection(2010-01-29) ;Jadsadapattarakul, Damrongsak ;Thanachayanont, Chanchana; In this work, sensing response, response time and recovery time for selective ethylene gas detection were improved by coating a layer of [0 1 0] highly preferred-orientation silicalite-1 polycrystals on SnO<inf>2</inf> thin film sensors. The sensors were prepared by primarily depositing SnO<inf>2</inf> on borosilicate glass substrates using ultrasonic spray pyrolysis technique. Conventional and [0 1 0] preferred orientations of silicalite-1 layers were then directly coated on the SnO<inf>2</inf> thin film sensors by hydrothermal crystallization technique with different gel compositions. The silicalite-1/SnO<inf>2</inf> thin film sensors were calcined at 550 °C in dry air. The crystal structure and surface morphology of SnO<inf>2</inf> and silicalite-1 layers were characterized by XRD and SEM techniques. XANES and TPR were used to verify oxidation state and reduction temperature of the SnO<inf>2</inf> thin film sensors, respectively. The interaction of C<inf>2</inf>H<inf>4</inf> and H<inf>2</inf>O with silicalite-1 was determined by TPD. The sensing performances, such as selectivity, dynamic range, response time and recovery time were evaluated for the C<inf>2</inf>H<inf>4</inf> and H<inf>2</inf>O. The results showed that the incorporated silicalite-1 layers readily improve the C<inf>2</inf>H<inf>4</inf> selectivity and dynamic range by preferential adsorption of C<inf>2</inf>H<inf>4</inf> molecules on the silicalite-1 filtering layers. The response time and recovery time for the [0 1 0] highly preferred-orientation silicalite-1/SnO<inf>2</inf> thin film sensor (t<inf>90%</inf>, 14 and 144 s) were shorter than those of the conventional one (t<inf>90%</inf>, 25 and 208 s). It is suggested that the [0 1 0] preferred-orientation silicalite-1, with a pore direction perpendicular to SnO<inf>2</inf> thin film surface, can accelerate the molecular diffusion and reduce the diffusion pathway of ethylene to the sensing film. © 2009 Elsevier B.V. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, High sensitive nanocrystal titanium nitride EG-FET pH sensor(2013-10-29) ;Rayanasukha, Yossawat ;Porntheeraphat, Supanit ;Bunjongpru, Win; Pankiew, ApirakSolid state pH-sensor device with high efficiency has successfully prepared by using TiN thin film as sensing membrane of extended gate field effect transistor (EG-FET) device. This research has described the physical properties and sensing characteristics of TiN membrane thin film which deposited on SiO<inf>2</inf>/Si substrate through reactive D.C. magnetron sputtering system. Thenanocrytal-TiNwith anatasestructure depended on substrate heating conditions was revealed from glancing angle x-ray diffraction. The I<inf>DS</inf>-V<inf>GS</inf> measurement in the standard buffer solutions showed that the sensitivity of fabricated TiN-EGFET pH deviceis 59.82mV/pH. © (2013) Trans Tech Publications, Switzerland. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Highly-sensitive optofluidics-based single-flow-channel refractometer structure(2011-12-01) ;Chaitavon, Kosom ;Sumriddetchkajorn, SarunThis paper shows how only a single-channel microfluidic chip when deployed in our interferometric optofluidics-based refractometer can offer a very high sensitivity of 6.1610 <sup>6</sup> RIU/pixel suitable for sensitive bio and chemical sensing applications. © 2011 IEEE. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Study on optical and electronic properties of Sn-doped ZnPc(2013-10-29); ;Sributr, Chaloempol ;Rojanasuwan, Sunit; Sn doped ZnPc films were deposited on intrinsic Si and glass substrates by organic source thermal co-evaporation technique with different deposition rates. Optical properties and electronic structure were characterized by UV-Vis spectroscopy and X-ray photoelectron spectroscopy (XPS) respectively. The UV-Vis results showed that phase transition of ZnPc from α- phase to β-phase occurred when Sn:ZnPc deposition rate is 0.3:0.7 or higher. XPS results indicated that the outer s electron of Sn atom is transferred to the ZnPc. Broadening of the C 1s spectra is observed with the increasing of Sn deposition rate. This broadening corresponds to the change of molecular environment surrounding carbon atoms in the Sn-doped ZnPc films. © (2013) Trans Tech Publications, Switzerland. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Efficiency of SPIONs functionalized with polyethylene glycol bis(amine) for heavy metal removal(2016-09-15) ;Wanna, Yongyuth ;Chindaduang, Anon ;Tumcharern, Gamolwan; Porntheerapat, SupanitHybrid magnetic nanoparticles based on poly(methylmethacrylate) (PMMA) and super-paramagnetic iron oxide nanopaticles (SPIONs) with selective surface modification has been developed for heavy metal removal by applying external magnetic fields. The nanoparticles were prepared by the emulsion polymerization technique in an aqueous suspension of SPIONs. The hydrolysis of carboxyl functional group was then applied for grafting polyethylene glycol bis(amine)(PEG-bis(amine)) onto the PMMA-coated SPIONs. The morphology, the chemical structure and the magnetic properties of the grafted nanoparticles were investigated. The efficiency of the hybrid nanoparticles for heavy metal removal were conducted on Pb(II), Hg(II), Cu(II) and Co(II) in aqueous solutions.The metal concentration in the solutions after separation by the hybrid nanoparticles was determined by inductively coupled plasma optical emission spectrometer (ICP-OES). The results show the heavy metal uptake ratios of 0.08, 0.04, 0.03, and 0.01 mM per gramme of the grafted SPIONs for Pb(II), Hg(II), Cu(II), and Co(II), respectively. A competitive removal of Cu(II), Pb(II), Co(II) and Hg(II) ions in mixed metal salt solutions has also been studied.The heavy metal removal efficiency of the hybrid nanoparitcles was found to depend on the cation radius, in accordance with capture of metal ions by the amine group. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Improved Efficiency of Polymer Solar Cells by means of Coating Hole Transporting Layer as Double Layer Deposition(2017-10-20) ;Chonsut, T.; ; ; Polymer solar cells is one of the promising technologies that gain tremendous attentions in the field of renewable energy. Optimization of thickness for each layer is an important factor determining the efficiency of the solar cells. In this work, the optimum thickness of Poly(3,4-ethylenedioxythione): poly(styrenesulfonate) (PEDOT:PSS), a famous polymer widely used as hole transporting layer in polymer solar cells, is determined through the analyzing of device's photovoltaic parameters, e.g. short circuit current density (J<inf>sc</inf>), open circuit voltage (V<inf>oc</inf>), fill factor (FF) as well as power conversion efficiency (PCE). The solar cells were prepared with multilayer of ITO/PEDOT:PSS/PCDTBT:PC<inf>70</inf>BM/TiO<inf>x</inf>/Al by rapid convective deposition. In such preparation technique, the thickness of the thin film is controlled by the deposition speed. The faster deposition speed is used, the thicker film is obtained. Furthermore, double layer deposition of PEDOT:PSS was introduced as an approach to improve solar cell efficiency. The results obviously reveal that, with the increase of PEDOT:PSS thickness, the increments of J<inf>sc</inf> and FF play the important role to improve PCE from 3.21% to 4.03%. Interestingly, using double layer deposition of PEDOT:PSS shows the ability to enhance the performance of the solar cells to 6.12% under simulated AM 1.5G illumination of 100 mW/cm<sup>2</sup>. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Modification of a photoanode by means of localized surface plasmon resonance from Au nanoparticles decorated on ZnO nanorods for photoelectrochemical applications(2019-01-01); ;Soyeux, Nathan ;Rattanawarinchai, Prapakorn ;Jessadaluk, SukittiyaKlamchuen, AnnopPhotoelectrochemical (PEC) activity is possibly enhanced by an increase in photocurrent generated from the photoanode. In this work, a modified photoanode that consists of zinc oxide nanorods (ZnO-NRs) decorated with gold nanoparticles (Au-NPs) is proposed to improve the generation of photocurrent. X-ray diffraction and scanning electron microscopy are employed to confirm the decoration of Au-NPs on well-aligned ZnO-NRs. A significant enhancement (∼4 times) in photocurrent density is obtained from the ZnO-NR photoanode decorated with Au-NPs compared to the bare ZnO-NR photoanode. Photoluminescence and UV-visible spectroscopy reveal that the improvement in photocurrent density results from (i) the decrease in charge recombination in the ZnO-NRs due to charge dissociation and (ii) the additional injection of charge from Au-NPs owing to localized surface plasmon resonance. This research presents the idea of taking the benefit from Au-NPs to enhance the photocurrent density in PEC applications through the decrease in charge recombination and the increase in charge injection.
