Wirunchit, Supamas
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Preferred name
Wirunchit, Supamas
Alternative Name
Wirunchit, S.
Main Affiliation
Email
supamas.wi@kmitl.ac.th
16 results
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Item type:Publication, Improved Efficiency of Polymer Solar Cells by means of Coating Hole Transporting Layer as Double Layer Deposition(2017-10-20); ; ; Polymer solar cells is one of the promising technologies that gain tremendous attentions in the field of renewable energy. Optimization of thickness for each layer is an important factor determining the efficiency of the solar cells. In this work, the optimum thickness of Poly(3,4-ethylenedioxythione): poly(styrenesulfonate) (PEDOT:PSS), a famous polymer widely used as hole transporting layer in polymer solar cells, is determined through the analyzing of device's photovoltaic parameters, e.g. short circuit current density (J<inf>sc</inf>), open circuit voltage (V<inf>oc</inf>), fill factor (FF) as well as power conversion efficiency (PCE). The solar cells were prepared with multilayer of ITO/PEDOT:PSS/PCDTBT:PC<inf>70</inf>BM/TiO<inf>x</inf>/Al by rapid convective deposition. In such preparation technique, the thickness of the thin film is controlled by the deposition speed. The faster deposition speed is used, the thicker film is obtained. Furthermore, double layer deposition of PEDOT:PSS was introduced as an approach to improve solar cell efficiency. The results obviously reveal that, with the increase of PEDOT:PSS thickness, the increments of J<inf>sc</inf> and FF play the important role to improve PCE from 3.21% to 4.03%. Interestingly, using double layer deposition of PEDOT:PSS shows the ability to enhance the performance of the solar cells to 6.12% under simulated AM 1.5G illumination of 100 mW/cm<sup>2</sup>. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Preparation of lead zirconate-lead nickel niobate ceramics by the reaction sintering process(2009-12-01); ; ; Laoratanakul, PitakThe perovskite structure of lead zirconate - lead nickel niobate ceramics, (1-x) PbZrO3-xPb(Ni1/3Nb2/3)O3 (PZ - PNN) at x between 0.00-0.50, has been prepared by the reaction-sintering process. The specimens were prepared directly from a mixture of their constituent oxide without any calcination step. The PZ - PNN ceramics could be obtained after 6 h sintering at 1,100-1,250°C. Crystal structure and phase transition of PZ-PNN were investigated by x-ray diffraction (XRD). XRD indicated that the structure of PZ-PNN ceramics is orthorhombic for a composition where x = 0.00, rhombohedral for compositions where x = 0.10 ≤ x ≤ 0.40 and pseudo-cubic for a composition where x = 0.50. The dielectric properties of the ceramics were measured as functions of both temperature and frequency. The results indicated that the transition temperature decreases with increasing PNN concentration. Furthermore, morphology and grain size evolution have been determined via a scanning electron microscope (SEM). Copyright © Taylor & Francis Group, LLC. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Study of optical and electrical properties of tin doped cobalt-phthalocyanine thin films prepared by thermal co-evaporation(2018-09-05); ; ; The aim of this research is to study the specific properties e.g. surface morphology, optical absorption as well as electrical conductivity of tin-doped cobalt-phthalocyanine (CoPc) thin film prepared by thermal co-evaporation. The concentration of tin metal dopant is controlled via evaporation rate during film's preparation. The change of tin quantity leads to the significant changes not only in morphology but also in molecular packing of the doped films. Moreover, the dramatic increase in both carrier mobility and carrier concentration should provide the enhancement in electrical conductivity of the doped films. By controlling the specific properties of the tin-doped CoPc thin film, the increasing efficiency of optoelectronic applications based on metal-phthalocyanine could be achieved. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Synthesis of ZnO nanoparticles by Ball-milling process for biological applications(2021-01-01); - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Study of nano Titanium (IV) oxide for Self-cleaning applications(2021-01-01); This research is study the fabrication of a composite film between Polydimethylsiloxane (PDMS) and Titanium (IV) oxide nanoparticles for self-cleaning applications via the spin coating process. This study has focused on the optimum ratio between PDMS and Titanium (IV) oxide and the optimum speed for the spin coating process, especially in order to obtain a composite film with outstanding self-cleaning surface properties. After that, the prepared composite films were studied by UV-Vis spectrometer, water contact angle measurement and solar simulator. Self-cleaning properties was investigated from the testing of wetting properties and measuring the water contact angle. Furthermore, the organic degradation properties were examined by degradation of methylene blue under UV light via solar. From this research was found that the PDMS/Titanium oxide (IV) at 4:3 ratio is the most optimum condition for the fabrication of a composite film by observing with the degradation of methylene blue has showed the highest the degradable efficiency is 55.59%. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Phase formation polycrystalline vanadium oxide via thermal annealing process under controlled nitrogen pressure(2017-10-20); ; ; This article provides an approach to improve and control crystal phases of the sputtering vanadium oxide (V<inf>x</inf>O<inf>y</inf>) thin films by post-thermal annealing process. Usually, as-deposited V<inf>x</inf>O<inf>y</inf> thin films at room temperature are amorphous phase: post-thermal annealing processes (400 °C, 2 hrs) under the various nitrogen (N<inf>2</inf>) pressures are applied to improve and control the crystal phase of V<inf>x</inf>O<inf>y</inf> thin films. The crystallinity of V<inf>x</inf>O<inf>y</inf> thin films changes from amorphous to α-V<inf>2</inf>O<inf>5</inf> phase or V<inf>9</inf>O<inf>17</inf> polycrystalline, which depend on the pressure of N<inf>2</inf> carrier during annealing process. Moreover, the electrical resistivity of the V<inf>x</inf>O<inf>y</inf> thin films decrease from 10<sup>5</sup> Ω cm (amorphous) to 6×10<sup>-1</sup> Ω cm (V<inf>9</inf>O<inf>17</inf>). Base on the results, our study show a simply method to improve and control phase formation of V<inf>x</inf>O<inf>y</inf> thin films<inf>.</inf> - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Influence of the annealing temperature on the organometallic halide perovskite phase formation via CH3NH3Cl as additive in sequential deposition process.(2019-01-01); ; ; Organometallic halide perovskite materials with the general formula ABX<inf>3</inf> have been recently interested as active layers in perovskite solar cells. It is well known that the O<inf>2</inf> is the main problem for fabricated perovskite solar cells. Usually, the perovskite thin film need to be prepared in the N<inf>2</inf> atmosphere or in the glove box. In this research, the metal halide perovskite CH<inf>3</inf>NH<inf>3</inf>PbI<inf>2</inf>Cl thin films were successfully deposited using spin-coating technique via a single step solution deposition and CH<inf>3</inf>NH<inf>3</inf>Cl as additive in sequential deposition process in the open air. The effect of annealing temperature on the organolead halide perovskite phase formation of CH<inf>3</inf>NH<inf>3</inf>PbI<inf>2</inf>Cl thin film was investigated. The phase formation as well as crystal structure were investigated by X-ray diffractometer, and we found that organolead halide perovskite thin film exhibited a pure phase perovskite without the unwanted phases. The crystallinity of the perovskite thin film was enhanced significantly by increasing the annealing temperature, and a single phase of the perovskite phase was observed by increment of the annealing temperature that is above 100<sup>O</sup>C. In addition to this, the growth of crystallinity in the halide perovskite thin film was increased with increasing heat treatment temperature. Furthermore, the morphology variation of the thin films were examined by Field Emission Scanning Electron Microscopy. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Development of solution-based electrodes from nanocomposite material between PEDOT:PSS and ITO nanoparticles(2017-01-01); ; ; Electrodes based on low-temperature preparation such as ink jet printing have been famously used in plastic electronic devices. The aim of this work is to investigate the specific properties of composite materials between nanoparticles of indium tin oxide (np-ITO) and poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) as an alternative electrode for plastic electronic devices. The composite materials were prepared as a function of np-ITO concentration varied from 1 to 20 w/v%. The 1x1 cm<sup>2</sup> hybrid electrodes were fabricated by drop casting method on the microscope slide. This method offers many advantages, including simple preparation, low manufacturing cost and short fabricating time. The electrical resistance of the hybrid films was measured using two-probe measurement. Moreover, the surface morphology of the composited film was explored by optical microscopy, scanning electron microscopy (SEM) and atomic force microscopy (AFM). The results clearly suggest that mixing np-ITO with PEDOT:PSS can significantly improve conductivity of the composited system. Average value of electrical resistance measured from np-ITO, PEDOT:PSS and composite film are 87.58 kΩ, 40.33 kΩ and 393 Ω, respectively. The significant reduction of film resistance can be explained by the conducting paths made up by PEDOT:PSS to connect np-ITO domain. - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Effect of lead nickel niobate substitution on phase transitions of lead zirconate ceramics prepared by the solid state reaction method(2008-01-01); - Some of the metrics are blocked by yourconsent settings
Item type:Publication, Crossover from antiferroelectric to normal ferroelectric behavior in lead zirconate - lead nickel niobate ceramics prepared by the reaction sintering process(2009-12-01); The lead zirconate - lead nickel niobate ceramics, (1-x)PbZrO3 - xPb(Ni1/3Nb2/3)O3 (PZ-PNN) with x = 0.00-0.10, have been prepared by reaction sintering. Without any calcination involved, the mixture of raw materials was pressed and sintered directly. The PZ-PNN ceramics could be obtained after 6 h sintering at 1,100-1,250°C. The crystal structure data obtained from XRD indicate that the PZ-PNN, where x = 0.00-0.10, successively transforms from orthorhombic to rhombohedral symmetry with an increase in the PNN concentration around x = 0.08. The antiferroelectric phase (AFE) → ferroelectric phase (FE) transition occurs in compositions of 0.0 ≤ x ≤ 0.08. The AFE → FE phase transition shifts to lower temperatures with higher compositions of x. The FE phase temperature range width increases with increased PNN. Copyright © Taylor & Francis Group, LLC.